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Título : 1,3-Dien-5-ynes: Versatile Building Blocks for the Synthesis of Carbo- and Heterocycles
Autor : Aguilar, Enrique
Sanz Díez, Roberto
Fernández Rodríguez, Manuel A.
García García, Patricia
Publicado en: Chemical Reviews, 2010, V. 116, n. 14, p. 8256–8311
Editorial : American Chemical Society
Fecha de publicación : jul-2016
Fecha de disponibilidad: 27-jul-2017
ISSN : 0009-2665
Resumen : 1,3-Dien-5-ynes have been extensively used as starting materials for the synthesis of a wide number of different carbo- and heterocycles. The aim of this review is to give an overview of their utility in organic synthesis, highlighting the variety of compounds that can be directly accessed from single reactions over these systems. Thus, cycloaromatization processes are initially commented, followed by reactions directed toward the syntheses of five-membered rings, other carbocycles and, finally, heterocycles. The diverse methodologies that have been developed for the synthesis of each of these types of compounds from 1,3-dien-5-ynes are presented, emphasizing the influence of the reaction conditions and the use of additional reagents in the outcome of the transformations.
URI : http://hdl.handle.net/10259/4274
Versión del editor: http://dx.doi.org/10.1021/acs.chemrev.6b00181
Aparece en las colecciones: Artículos SINTORG

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