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Título : Solid state hydrogen storage in alanates and alanate-based compounds: a review
Autor : Milanese, Chiara .
Garroni, Sebastiano
Gennari, Fabiana .
Marini, Amedeo .
Klassen, Thomas .
Dornheim, Martin .
Pistidda, Claudio .
Publicado en: Metals. 2018, V. 8, n. 8, 567
Editorial : MDPI
Fecha de publicación : ago-2018
ISSN : 2075-4701
DOI: 10.3390/met8080567
Resumen : The safest way to store hydrogen is in solid form, physically entrapped in molecular form in highly porous materials, or chemically bound in atomic form in hydrides. Among the different families of these compounds, alkaline and alkaline earth metals alumino-hydrides (alanates) have been regarded as promising storing media and have been extensively studied since 1997, when Bogdanovic and Schwickardi reported that Ti-doped sodium alanate could be reversibly dehydrogenated under moderate conditions. In this review, the preparative methods; the crystal structure; the physico-chemical and hydrogen absorption-desorption properties of the alanates of Li, Na, K, Ca, Mg, Y, Eu, and Sr; and of some of the most interesting multi-cation alanates will be summarized and discussed. The most promising alanate-based reactive hydride composite (RHC) systems developed in the last few years will also be described and commented on concerning their hydrogen absorption and desorption performance
Palabras clave: alanates
metal aluminum hydrides
solid state hydrogen storage
complex hydrides
reactive hydride composite
Materia: Materiales
Materials
Ensayos (Tecnología)
Testing
Licencia: https://creativecommons.org/licenses/by/4.0/
URI : http://hdl.handle.net/10259/4931
Versión del editor: https://doi.org/10.3390/met8080567
Aparece en las colecciones: Artículos ICCRAM

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