High-Pressure Volumetric Properties of the Binary Mixtures (Di-isopropyl Ether + n-Heptane or Methylcyclohexane)

Abstract

This work reports the experimental density data for the binary mixtures of n-heptane or methylcyclohexane + di-isopropyl ether, measured over the full composition range between 0.1 and 140 MPa, and for temperatures from 298.15 to 393.15 K, by means of a vibrating tube densitometer calibrated with an uncertainty of 0.0007 g·cm–3. Then, the experimental density data were fitted using a Tait-like equation to derive mixing thermodynamic coefficients, including the isobaric expansivity and isothermal compressibility. Finally, the excess volumes of the abovementioned binary mixtures were calculated, and their nonideal behavior was investigated.