2026-04-17T20:55:11Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/100432025-09-13T00:05:21Zcom_10259_7463com_10259_5086com_10259_2604col_10259_7464
Repositorio Institucional de la Universidad de Burgos
author
Molinero Abad, Begoña
author
Trachioti, Maria
author
Prodromidis, Mamas I.
author
Domínguez Renedo, Olga
author
Alonso Lomillo, Mª Asunción
2025-01-24T13:46:21Z
2025-01-24T13:46:21Z
2025-03
0013-4686
http://hdl.handle.net/10259/10043
10.1016/j.electacta.2025.145710
The evaluation of different gold nanoparticles (AuNPs) modified screen-printed carbon electrodes (SPCEs) for the determination of ethanethiol in wine is presented in this work. Two procedures, electrochemical and spark discharge modification, have been tested for depositing AuNPs onto the working electrode surface. A gel polymer membrane, based on the mixture of 1-n‑butyl‑3-methylimidazolium hexafluorophosphate (BMIM-PF6) and poly(vinylidene fluoride) (PVDF) in dimethyl sulfoxide, has been incorporated as a supporting electrolyte for the amperometric determination of the analyte in the gas phase. The developed sensors demonstrated high selectivity and sensitivity, having a detection capability of 80 μg/L (α = β = 0.05). They also exhibited a high degree of precision, with reproducibility values ranging from 0.3 to 7.6%. The different AuNP/SPCEs integrating a gel polymer membrane electrolyte have been successfully applied to the headspace amperometric determination of ethanethiol in various wine samples.
eng
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Ethanethiol
Screen-printed carbon electrodes
Gold nanoparticles
Spark discharge
Gas sensor
Room temperature ionic liquids
Wine analysis
Gold nanoparticle-based amperometric sensors integrating a gel polymer membrane electrolyte for the headspace determination of ethanethiol in wines
info:eu-repo/semantics/article
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Molinero-ea__2025.pdf