2026-04-29T09:27:12Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/103002025-03-12T01:05:29Zcom_10259_5822com_10259_5086com_10259_2604col_10259_5823

Inkjet Printed Disposable High‐Rate On‐Paper Microsupercapacitors Li, Zheng Ruiz Fernández, Virginia Mishukova, Viktoriia Wan, Qiansu Liu, Haomin Xue, Han Gao, Ying Cao, Gaolong Li, Yuanyuan Zhuang, Xiaodong Weissenrieder, Jonas Cheng, Shi Li, Jiantong Disposable electronics Electrochemically exfoliated graphene Graphene quantum dots Inkjet printing On-paper microsupercapacitors PEDOT:PSS Electroquímica Electrotecnia Electrochemistry Electrical engineering On-paper microsupercapacitors (MSCs) are a key energy storage component for disposable electronics that are anticipated to essentially address the increasing global concern of electronic waste. However, nearly none of the present on-paper MSCs combine eco-friendliness with high electrochemical performance (especially the rate capacity). In this work, highly reliable conductive inks based on the ternary composite of poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS), graphene quantum dots and graphene are developed for scalable inkjet printing of compact (footprint area ≈ 20 mm2) disposable MSCs on commercial paper substrates. Without any post treatment, the printed patterns attain a sheet resistance as low as 4 Ω ▫−1. The metal-free all-solid-state MSCs exhibit a maximum areal capacitance > 2 mF cm−2 at a high scan rate of 1000 mV s−1, long cycle life (>95% capacitance retention after 10 000 cycles), excellent flexibility, and long service time. Remarkably, the “totally metal-free” MSC arrays are fully inkjet printed on paper substrates and also exhibit high rate performance. The life cycle assessment indicates that these printed devices have much lower eco-toxicity and global warming potential than other on-paper MSCs. The authors acknowledge the financial support from the FormasFoundation through the Future Research Leaders Grant (No. 2016-00496), the ÅForsk Foundation (Grant No. 17-352), the SwedishResearch Council (Grant No. 2019-04731), the Olle Engkvist ByggmästareFoundation (Grant No. 2014/799), and the Swedish Foundation forInternational Cooperation in Research and Higher Education (STINT,CH2017-7284). 2025-03-11T07:54:18Z 2025-03-11T07:54:18Z 2021-10 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion 1616-301X http://hdl.handle.net/10259/10300 10.1002/adfm.202108773 1616-3028 eng Advanced Funcrional Materials. 2021, V. 32, n. 1, p. 2108773 https://doi.org/10.1002/adfm.202108773 Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess application/pdf Wiley https://riubu.ubu.es/bitstream/10259/10300/4/Li-afm_2021.pdf.jpg Hispana TEXT http://creativecommons.org/licenses/by-nc-nd/4.0/ RIUBU. Repositorio Institucional de la Universidad de Burgos http://hdl.handle.net/10259/10300