2026-04-29T08:29:40Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/103002025-03-12T01:05:29Zcom_10259_5822com_10259_5086com_10259_2604col_10259_5823

Li, Zheng 1b55e033-24f8-41e4-8b15-f9ec40c6fd68 500 Ruiz Fernández, Virginia 858 600 0000-0002-0466-0634 Mishukova, Viktoriia 72651af6-3bbd-4fe9-93cc-5207997f8a07 500 Wan, Qiansu 94d72bc5-52b8-40f9-8c9c-2f44d334773c 500 Liu, Haomin de52f241-9706-43f9-acfb-d0674062cd47 500 Xue, Han 8097949c-080a-4985-8005-8e8675f2c39b 500 Gao, Ying 4da018b5-5320-4db7-8a1b-35fbe3e6da8e 500 Cao, Gaolong 82037695-940f-4c47-a9d8-2e47e69a404d 500 Li, Yuanyuan 4db9c6cd-5087-45d6-ac74-58977e337879 500 Zhuang, Xiaodong adb181f5-5848-4811-9586-1d0b53ff33d8 500 Weissenrieder, Jonas 7b7b92e1-b378-4f2e-ba61-1f84988e95aa 500 Cheng, Shi 991b035d-8df0-44f3-bf57-976010104d58 500 Li, Jiantong b56a32ba-1de2-44bf-b2e0-388c4177ee33 500 2025-03-11T07:54:18Z 2025-03-11T07:54:18Z 2021-10 1616-301X http://hdl.handle.net/10259/10300 10.1002/adfm.202108773 1616-3028 On-paper microsupercapacitors (MSCs) are a key energy storage component for disposable electronics that are anticipated to essentially address the increasing global concern of electronic waste. However, nearly none of the present on-paper MSCs combine eco-friendliness with high electrochemical performance (especially the rate capacity). In this work, highly reliable conductive inks based on the ternary composite of poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS), graphene quantum dots and graphene are developed for scalable inkjet printing of compact (footprint area ≈ 20 mm2) disposable MSCs on commercial paper substrates. Without any post treatment, the printed patterns attain a sheet resistance as low as 4 Ω ▫−1. The metal-free all-solid-state MSCs exhibit a maximum areal capacitance > 2 mF cm−2 at a high scan rate of 1000 mV s−1, long cycle life (>95% capacitance retention after 10 000 cycles), excellent flexibility, and long service time. Remarkably, the “totally metal-free” MSC arrays are fully inkjet printed on paper substrates and also exhibit high rate performance. The life cycle assessment indicates that these printed devices have much lower eco-toxicity and global warming potential than other on-paper MSCs. The authors acknowledge the financial support from the FormasFoundation through the Future Research Leaders Grant (No. 2016-00496), the ÅForsk Foundation (Grant No. 17-352), the SwedishResearch Council (Grant No. 2019-04731), the Olle Engkvist ByggmästareFoundation (Grant No. 2014/799), and the Swedish Foundation forInternational Cooperation in Research and Higher Education (STINT,CH2017-7284). application/pdf eng Wiley Advanced Funcrional Materials. 2021, V. 32, n. 1, p. 2108773 https://doi.org/10.1002/adfm.202108773 Attribution-NonCommercial-NoDerivatives 4.0 Internacional http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Disposable electronics Electrochemically exfoliated graphene Graphene quantum dots Inkjet printing On-paper microsupercapacitors PEDOT:PSS Electroquímica Electrotecnia Electrochemistry Electrical engineering Inkjet Printed Disposable High‐Rate On‐Paper Microsupercapacitors info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Advanced Functional Materials 32 1 2108773 THUMBNAIL Li-afm_2021.pdf.jpg Li-afm_2021.pdf.jpg IM Thumbnail image/jpeg 3864 https://riubu.ubu.es/bitstream/10259/10300/4/Li-afm_2021.pdf.jpg e400660f29de58c41b6ab1dfa53da0d3 MD5 4 LICENSE license.txt license.txt text/plain; charset=utf-8 999 https://riubu.ubu.es/bitstream/10259/10300/3/license.txt b295bcbce42e2caabeb0c623d3860c06 MD5 3 CC-LICENSE license_rdf license_rdf application/rdf+xml; charset=utf-8 805 https://riubu.ubu.es/bitstream/10259/10300/2/license_rdf 4460e5956bc1d1639be9ae6146a50347 MD5 2 ORIGINAL Li-afm_2021.pdf Li-afm_2021.pdf application/pdf 3122093 https://riubu.ubu.es/bitstream/10259/10300/1/Li-afm_2021.pdf 23d89c0c9622d7ade74c118b37485bd7 MD5 1 10259/10300 oai:riubu.ubu.es:10259/10300 2025-03-12 02:05:29.371 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es 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