2026-04-22T15:06:14Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/105052025-05-29T00:05:14Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

00925njm 22002777a 4500 dc Gómez Gil, Sara author Suárez Pantiga, Samuel author Pedrosa Sáez, María de los Remedios author Sanz Díez, Roberto author 2024-10 A molybdenum-catalyzed synthesis of N-(hetero)aryl pyrroles directly from inexpensive and commonly available (hetero)nitroarenes via reduction with pinacol and annulation with 1,4-dicarbonyls or cyclobutane-1,2-diols has been described. The process does not require an inert atmosphere and tolerates the presence of air and water. This non-noble catalytic system shows high chemoselectivity, allowing a diverse range of potentially reducible functional groups such as alkynes, alkenes, halogens, cyano, and carbonyls. Moreover, this strategy enables the reuse of a waste byproduct as reactant, facilitating the formation of challenging 1,4-dicarbonyls from accessible cyclobutane-1,2-diols used as reducing agents. 1615-4150 http://hdl.handle.net/10259/10505 10.1002/adsc.202401170 1615-4169 Nitroarenes Pyrroles Reduction Molybdenum Glycols Molybdenum‐Catalyzed Direct Synthesis of Pyrroles from Nitroarenes with Glycols as Reductants