2026-04-21T11:06:03Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/105062025-05-29T00:05:19Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

Hernández Ruiz, Raquel Solas Luera, Marta Suárez Pantiga, Samuel Pedrosa Sáez, María de los Remedios Sanz Díez, Roberto 2025-05-28T07:31:13Z 2025-05-28T07:31:13Z 2025-05 1615-4150 http://hdl.handle.net/10259/10506 10.1002/adsc.202401387 1615-4169 A molybdenum-catalyzed deoxygenation of sulfoxides, pyridine and quinoline N-oxides, N-hydroxybenzotriazoles, as well as the reduction of nitroarenes to anilines, has been developed using monocyclic terpenes such as γ-terpinene as an environmentally benign hydrogen surrogate. The only byproducts generated are water and p-cymene, under neat reaction conditions in which the terpene acts as both solvent and reducing agent. These features make this approach a highly attractive and sustainable alternative for the reduction of S-O and N-O containing compounds. Additionally, the reaction exhibited excellent chemoselectivity, tolerating a wide variety of functional groups. Financial support from Junta de Castilla y León and FEDER (BU028P23) and Ministerio de Ciencia, Innovación y Universidades (PID2020-115789GB−C21, PID2023-148198NB−C21, and PDC2021-115789GB−C21) is gratefully acknowledged. R.H.-R. thanks Ministerio de Ciencia, Innovación y Universidades for a FPU predoctoral contract. M.S. thanks Junta de Castilla y León and FEDER for a postdoctoral contract. S.S.-P. thanks Ministerio de Ciencia, Innovación y Universidades and “NextGenerationEU”/PRTR EU for a Ramón y Cajal contract (RYC2021-031533-I). application/pdf eng Wiley Advanced Synthesis & Catalysis. 2025, V. 367, n. 9, p. e202401387 https://doi.org/10.1002/adsc.202401387 Atribución-NoComercial 4.0 Internacional http://creativecommons.org/licenses/by-nc/4.0/ info:eu-repo/semantics/openAccess γ‐Terpinene Molybdenum Reduction Sulfoxides Nitroarenes Química Chemistry γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N‐Oxides and Nitroarenes info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Advanced Synthesis & Catalysis 367 9 e202401387