2026-04-21T10:54:08Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/105062025-05-29T00:05:19Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

Hernández Ruiz, Raquel Solas Luera, Marta Suárez Pantiga, Samuel Pedrosa Sáez, María de los Remedios Sanz Díez, Roberto γ‐Terpinene Molybdenum Reduction Sulfoxides Nitroarenes A molybdenum-catalyzed deoxygenation of sulfoxides, pyridine and quinoline N-oxides, N-hydroxybenzotriazoles, as well as the reduction of nitroarenes to anilines, has been developed using monocyclic terpenes such as γ-terpinene as an environmentally benign hydrogen surrogate. The only byproducts generated are water and p-cymene, under neat reaction conditions in which the terpene acts as both solvent and reducing agent. These features make this approach a highly attractive and sustainable alternative for the reduction of S-O and N-O containing compounds. Additionally, the reaction exhibited excellent chemoselectivity, tolerating a wide variety of functional groups. 2025-05-28 2025-05-28 2025-05 info:eu-repo/semantics/article 1615-4150 http://hdl.handle.net/10259/10506 10.1002/adsc.202401387 1615-4169 eng Advanced Synthesis & Catalysis. 2025, V. 367, n. 9, p. e202401387 https://doi.org/10.1002/adsc.202401387 http://creativecommons.org/licenses/by-nc/4.0/ info:eu-repo/semantics/openAccess Atribución-NoComercial 4.0 Internacional Wiley