2026-04-21T08:58:10Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/105062025-05-29T00:05:19Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Hernández Ruiz, Raquel
277
600
0000-0001-5018-0845
Solas Luera, Marta
542
600
0000-0002-0052-7270
Suárez Pantiga, Samuel
544
600
0000-0002-4249-7807
Pedrosa Sáez, María de los Remedios
422
600
0000-0001-7083-8093
Sanz Díez, Roberto
531
600
0000-0003-2830-0892
2025-05-28T07:31:13Z
2025-05-28T07:31:13Z
2025-05
1615-4150
http://hdl.handle.net/10259/10506
10.1002/adsc.202401387
1615-4169
A molybdenum-catalyzed deoxygenation of sulfoxides, pyridine and quinoline N-oxides, N-hydroxybenzotriazoles, as well as the reduction of nitroarenes to anilines, has been developed using monocyclic terpenes such as γ-terpinene as an environmentally benign hydrogen surrogate. The only byproducts generated are water and p-cymene, under neat reaction conditions in which the terpene acts as both solvent and reducing agent. These features make this approach a highly attractive and sustainable alternative for the reduction of S-O and N-O containing compounds. Additionally, the reaction exhibited excellent chemoselectivity, tolerating a wide variety of functional groups.
Financial support from Junta de Castilla y León and FEDER (BU028P23) and Ministerio de Ciencia, Innovación y Universidades (PID2020-115789GB−C21, PID2023-148198NB−C21, and PDC2021-115789GB−C21) is gratefully acknowledged. R.H.-R. thanks Ministerio de Ciencia, Innovación y Universidades for a FPU predoctoral contract. M.S. thanks Junta de Castilla y León and FEDER for a postdoctoral contract. S.S.-P. thanks Ministerio de Ciencia, Innovación y Universidades and “NextGenerationEU”/PRTR EU for a Ramón y Cajal contract (RYC2021-031533-I).
application/pdf
eng
Wiley
Advanced Synthesis & Catalysis. 2025, V. 367, n. 9, p. e202401387
https://doi.org/10.1002/adsc.202401387
Atribución-NoComercial 4.0 Internacional
http://creativecommons.org/licenses/by-nc/4.0/
info:eu-repo/semantics/openAccess
γ‐Terpinene
Molybdenum
Reduction
Sulfoxides
Nitroarenes
Química
Chemistry
γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N‐Oxides and Nitroarenes
info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Advanced Synthesis & Catalysis
367
9
e202401387
THUMBNAIL
Hernández-as&c_2025.pdf.jpg
Hernández-as&c_2025.pdf.jpg
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Hernández-as&c_2025.pdf
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oai:riubu.ubu.es:10259/10506
2025-05-29 02:05:19.34
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
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