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oai:riubu.ubu.es:10259/110922025-11-22T01:05:37Zcom_10259_5822com_10259_5086com_10259_2604col_10259_5823

Laaksonen, Timo 7d33ea79-eebc-445d-a156-2f9437804812 600 Ruiz Fernández, Virginia 858 600 0000-0002-0466-0634 Murtomäki, Lasse 513f907e-c339-4190-a0af-00434432e37a Quinn, Bernadette M. 01d445cc-3ccf-41c0-b1b3-d5dd4efb84f8 600 2025-11-21T12:06:42Z 2025-11-21T12:06:42Z 2007-06 0002-7863 https://hdl.handle.net/10259/11092 10.1021/ja0720107 1520-5126 For hydrophobic redox films immersed in aqueous electrolyte, electron transfer at the electrode/film interface is coupled to ion transfer across the film/solution interface. Here we consider how differences in ion solvation in the film versus the electrolyte phase can control the apparent redox properties of model electroactive thin films. Funding from the Academy of Finland (B.Q. and T.L.) and Ministerio de Educación y Ciencia (Juan de la Cierva contract, V.R.) is acknowledged. application/pdf eng American Chemical Society Journal of the American Chemical Society. 2007, V. 129, n. 25, p. 7732–7733 https://doi.org/10.1021/ja0720107 Anions Hydrophobicity Interfaces Ions Thin films Nanotecnología Electroquímica Nanotechnology Electrochemistry Nanoparticle Film ChargingIon Rectified or Ion Limited? info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion info:eu-repo/semantics/openAccess Journal of the American Chemical Society 129 25 7732 7733 THUMBNAIL Laaksonen-JACS_2007.pdf.jpg Laaksonen-JACS_2007.pdf.jpg IM Thumbnail image/jpeg 4594 https://riubu.ubu.es/bitstream/10259/11092/3/Laaksonen-JACS_2007.pdf.jpg 212dac33db7fe27f2b830c906f473576 MD5 3 LICENSE license.txt license.txt text/plain; charset=utf-8 999 https://riubu.ubu.es/bitstream/10259/11092/2/license.txt b295bcbce42e2caabeb0c623d3860c06 MD5 2 ORIGINAL Laaksonen-JACS_2007.pdf Laaksonen-JACS_2007.pdf application/pdf 336358 https://riubu.ubu.es/bitstream/10259/11092/1/Laaksonen-JACS_2007.pdf 8595c33533d3e4ab870e0469c710c486 MD5 1 10259/11092 oai:riubu.ubu.es:10259/11092 2025-11-22 02:05:37.725 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es 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