2026-05-08T22:53:12Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/114372026-02-27T01:05:46Zcom_10259_4323com_10259_5086com_10259_2604col_10259_4330

Alcalde García, Rafael T. Huerta Sainz, Sergio de la Diez Cabanes, Valentin Escobedo Monge, María Antonieta Trenzado, José Luis Atilhan, Mert Bol Arreba, Alfredo Aparicio Martínez, Santiago 2026-02-26T07:48:08Z 2026-02-26T07:48:08Z 2025-11 0167-7322 https://hdl.handle.net/10259/11437 10.1016/j.molliq.2025.128412 This study presents a comprehensive thermophysical characterization of hydrated deep eutectic solvents (DESs) composed of choline chloride (ChCl) and four hydrogen bond donors (HBDs): citric acid, malic acid, fructose, and ethylene glycol in equimolar ratios. By introducing 2, 10, and 22 wt% water—spanning key hydration regimes where DESs structure is progressively altered—we systematically quantify the effects of hydration on density, viscosity, electrical conductivity, thermal conductivity, and refractive index over a wide temperature range. Results demonstrate that water addition leads to a dramatic reduction in viscosity, particularly for bio-derived HBDs, enhancing processability and enabling practical applications. The ChCl:citric acid DESs maintains high structural cohesion upon hydration, reflected in persistent cooperative dynamics and high activation energy, whereas the synthetic ethylene glycol system exhibits predictable, tunable behavior, ideal for engineered fluid systems. Electrical conductivity increases non-linearly with water content, accompanied by a transition from fragile to strong liquid behavior. Derived parameters—molecular volume, thermal expansion coefficient, and excess molar volumes—reveal non-ideal mixing behavior and structural reorganization. Our findings define structure–property correlations critical for optimizing DESs formulations, offering a foundation for application-specific solvent engineering in energy, electrochemistry, and separation technologies. This research was funded by European Union (Horizon 2020 program, project WORLD: H2020-MSCA-RISE-2019-WORLD-GA-873005), and Agencia Estatal de Investigación (Project NADESforPFAS: PID2022-142405OB-I00). application/pdf eng Elsevier Journal of Molecular Liquids. 2025, V. 437, Part A, 128412 https://doi.org/10.1016/j.molliq.2025.128412 Atribución 4.0 Internacional http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Deep eutectic solvents Thermophysical properties Choline chloride Hydration effects Bio-based hydrogen bond donors Química física Disolventes Chemistry, Physical and theoretical Solvents Beyond the blend: Unveiling the thermophysical fingerprints of hydrated choline chloride deep eutectic systems with bio-derived and synthetic hydrogen bond donors info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Journal of Molecular Liquids 437 128412