<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-04-17T12:03:40Z</responseDate><request verb="GetRecord" identifier="oai:riubu.ubu.es:10259/3799" metadataPrefix="etdms">https://riubu.ubu.es/oai/request</request><GetRecord><record><header><identifier>oai:riubu.ubu.es:10259/3799</identifier><datestamp>2021-11-10T09:38:24Z</datestamp><setSpec>com_10259_3593</setSpec><setSpec>com_10259_5086</setSpec><setSpec>com_10259_2604</setSpec><setSpec>col_10259_3594</setSpec></header><metadata><thesis xmlns="http://www.ndltd.org/standards/metadata/etdms/1.0/" xmlns:doc="http://www.lyncode.com/xoai" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.ndltd.org/standards/metadata/etdms/1.0/ http://www.ndltd.org/standards/metadata/etdms/1.0/etdms.xsd">
<title>Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles</title>
<creator>Álvarez Manuel, Estela</creator>
<creator>Miguel, Delia</creator>
<creator>García García, Patricia</creator>
<creator>Fernández Rodríguez, Manuel A.</creator>
<creator>Rodríguez, Félix</creator>
<creator>Sanz Díez, Roberto</creator>
<subject>catalysis</subject>
<subject>gold</subject>
<subject>indoles</subject>
<subject>Nazarov cyclizations</subject>
<subject>selectivity</subject>
<description>The selectivity of our previously described gold-catalyzed tandem reaction, 1,2-indole migration followed by aura-iso-Nazarov cyclization, of 3-propargylindoles bearing (hetero)aromatic substituents at both the propargylic and terminal positions, was reversed by the proper choice of the catalyst and the reaction conditions. Thus, 3-(inden-2-yl)indoles, derived from an aura-Nazarov cyclization (instead of an aura-iso-Nazarov cyclization), were obtained in moderate to good yields from a variety of 3-propargylindoles</description>
<date>2015-07-27</date>
<date>2015-07-27</date>
<date>2011-06</date>
<type>info:eu-repo/semantics/article</type>
<identifier>1860-5397</identifier>
<identifier>http://hdl.handle.net/10259/3799</identifier>
<identifier>10.3762/bjoc.7.89</identifier>
<language>eng</language>
<relation>Beilstein Journal of Organic Chemistry. 2011, v. 7, p. 786–793</relation>
<relation>Gold catalysis for organic synthesis</relation>
<relation>http://dx.doi.org/10.3762/bjoc.7.89</relation>
<relation>info:eu-repo/grantAgreement/MICINN/CTQ2010-15358</relation>
<relation>info:eu-repo/grantAgreement/MICINN/CTQ2009-09949</relation>
<relation>info:eu-repo/grantAgreement/JCyL/BU021A09</relation>
<relation>info:eu-repo/grantAgreement/JCyL/GR-172</relation>
<rights>http://creativecommons.org/licenses/by/4.0/</rights>
<rights>Este documento está sujeto a una licencia de uso Creative Commons, por la cual está permitido hacer copia, distribuir, comunicar públicamente, remezclar, transformar y crear a partir del material&#xd;
para cualquier finalidad, incluso comercial, siempre que se cite al autor original,  se proporcione un enlace a la licencia y se indique si se han realizado cambios</rights>
<rights>info:eu-repo/semantics/openAccess</rights>
<rights>Attribution 4.0 International</rights>
<publisher>Beilstein-Institut</publisher>
</thesis></metadata></record></GetRecord></OAI-PMH>