2026-04-17T12:07:05Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/37992021-11-10T09:38:24Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

00925njm 22002777a 4500 dc Álvarez Manuel, Estela author Miguel, Delia author García García, Patricia author Fernández Rodríguez, Manuel A. author Rodríguez, Félix author Sanz Díez, Roberto author 2011-06 The selectivity of our previously described gold-catalyzed tandem reaction, 1,2-indole migration followed by aura-iso-Nazarov cyclization, of 3-propargylindoles bearing (hetero)aromatic substituents at both the propargylic and terminal positions, was reversed by the proper choice of the catalyst and the reaction conditions. Thus, 3-(inden-2-yl)indoles, derived from an aura-Nazarov cyclization (instead of an aura-iso-Nazarov cyclization), were obtained in moderate to good yields from a variety of 3-propargylindoles 1860-5397 http://hdl.handle.net/10259/3799 10.3762/bjoc.7.89 catalysis gold indoles Nazarov cyclizations selectivity Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles