2026-04-29T16:00:04Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/38562021-11-10T09:38:17Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

Ibáñez Martínez, David 290 500 Plana, Daniela . dd3876ef-a613-4e9e-945a-71e67bf749ee 500 Heras, Aránzazu 273 500 Fermín, David J. . ee63ef3a-f03f-40aa-8c03-afbf3583df38 500 Colina, Álvaro 122 500 2015-09-29T09:36:28Z 2015-09-29T09:36:28Z 2015-05 1388-2481 http://hdl.handle.net/10259/3856 10.1016/j.elecom.2015.02.012 In-situ Raman spectroscopy is implemented for the first time to monitor dynamic charge transfer processes at polarisable interfaces between two immiscible electrolyte solutions (ITIES) in real time. A custom-designed new electrochemical cell is described which allows probing the Raman signals of ferroin ions as a function of the potential applied across the water|1,2-dichlorobenzene (DCB) interface. This approach is also used for investigating the heterogeneous electron transfer reaction involving dimethylferrocene in DCB and potassium hexacyanoferrate (II/III) in the aqueous phase. The evolution of the Raman signals during potentiodynamic measurements is recorded in real-time with a resolution of a few seconds. Junta de Castilla y Leon (GR71, BU349-U13) and Ministerio de Economia y Competitividad (CTQ2010-17127) is gratefully acknowledged. D.I. thanks Ministerio de Economia y Competitividad for his predoctoral FPI fellowship. D.P. and D.J.F. acknowledge financial support from the EPSRC (grant EP/K007025/1) application/pdf eng Elsevier Electrochemistry Communications. 2015, V. 54, p. 14–17 http://dx.doi.org/10.1016/j.elecom.2015.02.012 info:eu-repo/grantAgreement/JCyL/BU349-U13 info:eu-repo/grantAgreement/MINECO/CTQ2010-17127 info:eu-repo/grantAgreement/JCyL/GR71 http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Liquid/liquid interfaces Ion transfer Electron transfer In-situ Raman spectroscopy Química analítica Chemistry, Analytic Monitoring charge transfer at polarisable liquid/liquid interfaces employing time-resolved Raman spectroelectrochemistry info:eu-repo/semantics/article info:eu-repo/semantics/submittedVersion TEXT Ibáñez-EC_2015.pdf.txt Ibáñez-EC_2015.pdf.txt Extracted text text/plain 0 https://riubu.ubu.es/bitstream/10259/3856/5/Ib%c3%a1%c3%b1ez-EC_2015.pdf.txt d41d8cd98f00b204e9800998ecf8427e MD5 5 THUMBNAIL Ibáñez-EC_2015.pdf.jpg Ibáñez-EC_2015.pdf.jpg IM Thumbnail image/jpeg 4298 https://riubu.ubu.es/bitstream/10259/3856/4/Ib%c3%a1%c3%b1ez-EC_2015.pdf.jpg 40eb2295fb0183c86c1f08309a869512 MD5 4 LICENSE license.txt license.txt text/plain; charset=utf-8 1362 https://riubu.ubu.es/bitstream/10259/3856/2/license.txt 5d013bfa6e473ff0db22cd82a4d71a70 MD5 2 ORIGINAL Ibáñez-EC_2015.pdf Ibáñez-EC_2015.pdf application/pdf 453309 https://riubu.ubu.es/bitstream/10259/3856/3/Ib%c3%a1%c3%b1ez-EC_2015.pdf c78755190fd722932e6bac52b60cecb8 MD5 3 10259/3856 oai:riubu.ubu.es:10259/3856 2021-11-10 10:38:17.902 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es 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