2026-04-17T23:18:00Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/38902022-04-29T11:09:58Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

García Bartolomé, Nuria García García, Patricia Fernández Rodríguez, Manuel A. Rubio Presa, Rubén Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto 2015-12-01T12:35:17Z 2015-12-01T12:35:17Z 2012-02 1615-4150 http://hdl.handle.net/10259/3890 10.1002/adsc.201100877 Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021 A09 and GR-172) for financial support. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts This is the peer reviewed version of the following article:García, N., García-García, P., Fernández-Rodríguez, M. A., Rubio, R., Pedrosa, M. R., Arnáiz, F. J. and Sanz, R. (2012), Pinacol as a New Green Reducing Agent: Molybdenum- Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics. Adv. Synth. Catal., 354: 321–327. doi: 10.1002/adsc.201100877 , which has been published in final form at 10.1002/adsc.201100877. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving application/pdf eng Wiley-VCH Verlag Advanced Synthesis & Catalysis. 2012, V. 354, n. 2-3, p. 321–327 http://dx.doi.org/10.1002/adsc.201100877 info:eu-repo/grantAgreement/MICINN/CTQ2010-15358 info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU info:eu-repo/grantAgreement/JCyL/BU021 A09 info:eu-repo/grantAgreement/JCyL/GR-172 chemoselectivity molybdenum nitro compounds reduction sulfoxides Química orgánica Chemistry, Organic Pinacol as a new green reducing agent: molybdenum-catalyzed chemoselective reduction of sulfoxides and nitroaromatics info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion info:eu-repo/semantics/openAccess