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oai:riubu.ubu.es:10259/38902022-04-29T11:09:58Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

Pinacol as a new green reducing agent: molybdenum-catalyzed chemoselective reduction of sulfoxides and nitroaromatics García Bartolomé, Nuria García García, Patricia Fernández Rodríguez, Manuel A. Rubio Presa, Rubén Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto chemoselectivity molybdenum nitro compounds reduction sulfoxides Química orgánica Chemistry, Organic Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021 A09 and GR-172) for financial support. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts This is the peer reviewed version of the following article:García, N., García-García, P., Fernández-Rodríguez, M. A., Rubio, R., Pedrosa, M. R., Arnáiz, F. J. and Sanz, R. (2012), Pinacol as a New Green Reducing Agent: Molybdenum- Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics. Adv. Synth. Catal., 354: 321–327. doi: 10.1002/adsc.201100877 , which has been published in final form at 10.1002/adsc.201100877. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving 2015-12-01T12:35:17Z 2015-12-01T12:35:17Z 2012-02 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion 1615-4150 http://hdl.handle.net/10259/3890 10.1002/adsc.201100877 eng Advanced Synthesis & Catalysis. 2012, V. 354, n. 2-3, p. 321–327 http://dx.doi.org/10.1002/adsc.201100877 info:eu-repo/grantAgreement/MICINN/CTQ2010-15358 info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU info:eu-repo/grantAgreement/JCyL/BU021 A09 info:eu-repo/grantAgreement/JCyL/GR-172 info:eu-repo/semantics/openAccess application/pdf Wiley-VCH Verlag https://riubu.ubu.es/bitstream/10259/3890/4/Garc%c3%ada-ASC_2012.pdf.jpg Hispana TEXT http://rightsstatements.org/vocab/CNE/1.0/ RIUBU. Repositorio Institucional de la Universidad de Burgos http://hdl.handle.net/10259/3890