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<title>Pinacol as a new green reducing agent: molybdenum-catalyzed chemoselective reduction of sulfoxides and nitroaromatics</title>
<creator>García Bartolomé, Nuria</creator>
<creator>García García, Patricia</creator>
<creator>Fernández Rodríguez, Manuel A.</creator>
<creator>Rubio Presa, Rubén</creator>
<creator>Pedrosa Sáez, María de los Remedios</creator>
<creator>Arnáiz García, Francisco Javier</creator>
<creator>Sanz Díez, Roberto</creator>
<subject>chemoselectivity</subject>
<subject>molybdenum</subject>
<subject>nitro compounds</subject>
<subject>reduction</subject>
<subject>sulfoxides</subject>
<description>Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions</description>
<date>2015-12-01</date>
<date>2015-12-01</date>
<date>2012-02</date>
<type>info:eu-repo/semantics/article</type>
<identifier>1615-4150</identifier>
<identifier>http://hdl.handle.net/10259/3890</identifier>
<identifier>10.1002/adsc.201100877</identifier>
<language>eng</language>
<relation>Advanced Synthesis &amp; Catalysis. 2012, V. 354, n. 2-3, p. 321–327</relation>
<relation>http://dx.doi.org/10.1002/adsc.201100877</relation>
<relation>info:eu-repo/grantAgreement/MICINN/CTQ2010-15358</relation>
<relation>info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU</relation>
<relation>info:eu-repo/grantAgreement/JCyL/BU021 A09</relation>
<relation>info:eu-repo/grantAgreement/JCyL/GR-172</relation>
<rights>info:eu-repo/semantics/openAccess</rights>
<publisher>Wiley-VCH Verlag</publisher>
</thesis></metadata></record></GetRecord></OAI-PMH>