2026-04-29T07:47:00Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/42892021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

García Bartolomé, Nuria Rubio Presa, Rubén García García, Patricia Fernández Rodríguez, Manuel A. Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto 2016-12-01T11:24:42Z 2017-04-21T02:45:06Z 2016-04 1463-9262 http://hdl.handle.net/10259/4289 10.1039/c5gc02862k A catalytic methodology for the oxidative cleavage of vicinal diols is described as an advantageous alternative in terms of the environmental impact on classical methods involving toxic oxidants. The novel strategy is based on the use of dioxomolybdenum(VI) complexes as catalysts and dimethyl sulfoxide (DMSO) as an oxidant and displays high selectivity and a broad scope for glycol cleavage. In addition, the developed system is also useful for the oxidation of acyloins to diketones. Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2013-48937-C2-1-P) and Junta de Castilla y León (BU237U13) application/pdf eng Royal Society of Chemistry Green Chemistry. 2016, V. 18, n. 8, p. 2335-2340 http://dx.doi.org/10.1039/c5gc02862k info:eu-repo/grantAgreement/MINECO-FEDER/CTQ2013-48937-C2-1-P info:eu-repo/grantAgreement/JCyL/BU237U13 Química orgánica Chemistry, Organic A Selective, Efficient and Environmentally Friendly Method for the Oxidative Cleavage of Glycols info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion info:eu-repo/semantics/openAccess