2026-04-29T04:12:51Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/42892021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

00925njm 22002777a 4500 dc García Bartolomé, Nuria author Rubio Presa, Rubén author García García, Patricia author Fernández Rodríguez, Manuel A. author Pedrosa Sáez, María de los Remedios author Arnáiz García, Francisco Javier author Sanz Díez, Roberto author 2016-04 A catalytic methodology for the oxidative cleavage of vicinal diols is described as an advantageous alternative in terms of the environmental impact on classical methods involving toxic oxidants. The novel strategy is based on the use of dioxomolybdenum(VI) complexes as catalysts and dimethyl sulfoxide (DMSO) as an oxidant and displays high selectivity and a broad scope for glycol cleavage. In addition, the developed system is also useful for the oxidation of acyloins to diketones. 1463-9262 http://hdl.handle.net/10259/4289 10.1039/c5gc02862k A Selective, Efficient and Environmentally Friendly Method for the Oxidative Cleavage of Glycols