2026-04-29T08:25:43Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/42892021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

A Selective, Efficient and Environmentally Friendly Method for the Oxidative Cleavage of Glycols García Bartolomé, Nuria Rubio Presa, Rubén García García, Patricia Fernández Rodríguez, Manuel A. Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto Química orgánica Chemistry, Organic A catalytic methodology for the oxidative cleavage of vicinal diols is described as an advantageous alternative in terms of the environmental impact on classical methods involving toxic oxidants. The novel strategy is based on the use of dioxomolybdenum(VI) complexes as catalysts and dimethyl sulfoxide (DMSO) as an oxidant and displays high selectivity and a broad scope for glycol cleavage. In addition, the developed system is also useful for the oxidation of acyloins to diketones. Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2013-48937-C2-1-P) and Junta de Castilla y León (BU237U13) 2016-12-01T11:24:42Z 2017-04-21T02:45:06Z 2016-04 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion 1463-9262 http://hdl.handle.net/10259/4289 10.1039/c5gc02862k eng Green Chemistry. 2016, V. 18, n. 8, p. 2335-2340 http://dx.doi.org/10.1039/c5gc02862k info:eu-repo/grantAgreement/MINECO-FEDER/CTQ2013-48937-C2-1-P info:eu-repo/grantAgreement/JCyL/BU237U13 info:eu-repo/semantics/openAccess application/pdf Royal Society of Chemistry