2026-05-12T02:18:22Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/42902021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

A practical and chemoselective Mo-catalysed sulfoxide reduction protocol using a 3- mercaptopropyl-functionalized silica gel (MPS) García Bartolomé, Nuria Fernández Rodríguez, Manuel A. García García, Patricia Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto Química orgánica Chemistry, Organic A convenient sulfoxide deoxygenation procedure using a mercaptopropyl-functionalized silica gel as the reducing agent is described. This new protocol based on a heterogeneous reagent displays broad scope and tolerance to reducible functional groups and, from an experimental point of view, enhances previous methods by simplifying the isolation of the sulfide to a simple filtration Ministerio de Econom´ıa y Competitividad (MINECO) and FEDER (CTQ2013-48937-C2-1P) and Junta de Castilla y Le´on (BU237U13) 2016-12-01T12:29:26Z 2017-03-07T03:45:06Z 2016-03 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion 2046-2069 http://hdl.handle.net/10259/4290 10.1039/c6ra03106d eng RSC Advances. 2016, V. 6, n. 32, p. 27083-27086 http://dx.doi.org/10.1039/c6ra03106d info:eu-repo/grantAgreement/MINECO-FEDER/CTQ2013-48937-C2-1P info:eu-repo/grantAgreement/JCyL/BU237U13 info:eu-repo/semantics/openAccess application/pdf Royal Society of Chemistry