2026-04-28T23:54:39Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/45282021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

Rubio Presa, Rubén 493 500 Fernández Rodríguez, Manuel A. 174 500 Pedrosa Sáez, María de los Remedios 422 500 Arnáiz García, Francisco Javier 38 500 Sanz Díez, Roberto 531 500 2017-07-13T09:28:47Z 2018-05-17T02:45:07Z 2017-05 1615-4150 http://hdl.handle.net/10259/4528 10.1002/adsc.201700071 A molybdenum-catalyzed deoxygenationof pyridine N -oxides and N-hydroxybenzotriazoles,as well as other azole N-oxides, has been developedusing pinacol as an environmentally friendly oxo-acceptor. The only by-products are acetone andwater making the process a convenient alternativeto established protocols in terms of waste gener-ation. The reaction is highly chemose lective and avariety of functional groups are tolerated. Theprocesses are usually very clean allowing theisolation of the pure deoxygenated products after asimple extraction in most cases. Ministerio de Economı´ayCompetitividad (MINECO) (CTQ2013-48937-C2-1-P,CTQ2015-70371-REDT, and CTQ2016-75023-C2-1-P) andJunta de Castilla y Leo´n and FEDER (BU076U16) This is the peer reviewed version of the following article: R. Rubio-Presa, M. A. Fernández-Rodríguez, M. R. Pedrosa, F. J. Arnáiz, R. Sanz, Adv. Synth. Catal. 2017, 359, 1752. doi: 10.1002/adsc.201700071, which has been published in final form at 10.1002/adsc.201700071. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving application/pdf eng Wiley-VCH Verlag Advanced Synthesis & Catalysis. 2017, V. 359, n. 10, p. 1752–1757 http://dx.doi.org/10.1002/adsc.201700071 amine N-oxides deoxygenation molyb-denum microwave heating N-hydroxybenzotria-zoles Química orgánica Chemistry, Organic Molybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agent info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion info:eu-repo/semantics/openAccess THUMBNAIL Rubio-ASC_2017.pdf.jpg Rubio-ASC_2017.pdf.jpg IM Thumbnail image/jpeg 3778 https://riubu.ubu.es/bitstream/10259/4528/4/Rubio-ASC_2017.pdf.jpg 0ccb7b10a2af4c8100be440b6199c63d MD5 4 ORIGINAL Rubio-ASC_2017.pdf Rubio-ASC_2017.pdf application/pdf 2809747 https://riubu.ubu.es/bitstream/10259/4528/1/Rubio-ASC_2017.pdf 8b8e453728bd31bdb742b08901d716f7 MD5 1 LICENSE license.txt license.txt text/plain; charset=utf-8 999 https://riubu.ubu.es/bitstream/10259/4528/2/license.txt b295bcbce42e2caabeb0c623d3860c06 MD5 2 TEXT Rubio-ASC_2017.pdf.txt Rubio-ASC_2017.pdf.txt Extracted text text/plain 23978 https://riubu.ubu.es/bitstream/10259/4528/3/Rubio-ASC_2017.pdf.txt a8455dc6e86c2921c1472502626783ae MD5 3 10259/4528 oai:riubu.ubu.es:10259/4528 2021-11-10 10:38:25.068 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es 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