2026-04-22T15:07:38Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/47812024-06-12T11:47:26Zcom_10259_4323com_10259_5086com_10259_2604col_10259_4330
Altamash, Tausif .
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500
Nasser, Mustafa S.
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Elhamarnah, Yousef
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500
Magzou, Musaab .
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500
Ullah, Ruh .
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Qiblawey, Hazim .
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Aparicio Martínez, Santiago
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0000-0001-9996-2426
Atilhan, Mert
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2018-05-15T08:39:25Z
2018-04
2020-04
0167-7322
http://hdl.handle.net/10259/4781
10.1016/j.molliq.2018.02.049
Natural deep eutectic solvent (NADES) produced herein this work by mixing betaine and alanine with lactic acid and malic acid with 1:1 M mixing ratios. Thermophysical properties including water content, thermal stability, density and gas solubility of CO2 and N2 were experimented at different isotherms for wide pressures range up to 50 bars. Moreover, detailed rheological experiments were conducted on the studied materials to obtain viscosity and deduce the dynamic flow behavior. A pressure driven physisorption mechanism was observed for the studied systems. Betaine based NADES materials showed superior carbon dioxide and nitrogen solubility when they are mixed with lactic acid. On the other hand, the rheological experimental results show shear-thinning effect in which the η is decreasing with shear rate at all temperatures. Low viscosity profiles NADES assure the less mass transfer resistance for lactic acid based NADES systems and it also confirmed that the high CO2 and N2 solubility for lactic acid based NADES samples.
NPRP grant # 6-330-2-140 from the Qatar National Research Fund (a member of Qatar Foundation) and by Ministerio de Economía y Competitividad (Spain, project CTQ2013-40476-R).
application/pdf
eng
Elsevier
Journal of Molecular Liquids. 2018, V. 256, p. 286-295
https://doi.org/10.1016/j.molliq.2018.02.049
info:eu-repo/grantAgreement/MINECO/CTQ2013-40476-R
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
Deep eutectic solvents
Natural products
Gas solubility
Rheology
Chemistry, Physical and theoretical
Química física
Gas solubility and rheological behavior study of betaine and alanine based natural deep eutectic solvents (NADES)
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
CC-LICENSE
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10259/4781
oai:riubu.ubu.es:10259/4781
2024-06-12 13:47:26.344
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
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