2026-06-29T20:50:33Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/48852026-02-06T12:54:43Zcom_10259_4365com_10259_5086com_10259_2604com_10259_4363col_10259_4366col_10259_4364
Repositorio Institucional de la Universidad de Burgos
author
Vaquero Gutiérrez, Mónica
author
Ruiz Riaguas, Alba
author
Martínez Alonso, Marta
author
Jalón Sotés, Félix Ángel
author
Manzano, Blanca R. .
author
Rodríguez, Ana M. .
author
García Herbosa, Gabriel
author
Carbayo Martín, Mª Aránzazu
author
García Ruiz, Begoña
author
Espino Ordóñez, Gustavo
2018-08-27T08:18:09Z
2019-07-25T02:45:07Z
2018-07
0947-6539
http://hdl.handle.net/10259/4885
10.1002/chem.201801173
A new family of heteroleptic bis-cyclometalated IrIII
complexes with formula [Ir(C
_
N)2(N
_
N)]Cl (C
_
N=2-phenylpyridinate
and N
_
N=2,2’-dipyridylamine or N-benzylated 2,2’-dipyridylamines,
were synthesized, characterized, and successfully
used as photosensitizers in the catalytic photooxidation of
an array of dialkyl, dibenzyl, alkyl aryl, and diaryl sulfides, as
well as sulfur-containing amino acids. Furthermore, the reactions
proceeded with optimal chemoselectivity, and atom
economy under mild conditions. Experimental observations
support a dual mechanism in which singlet oxygen and superoxide
are the actual oxidants.
eng
Selective photooxidation of sulfides catalyzed by bis‐cyclometalated IrIII photosensitizers bearing 2,2′‐dipyridylamine‐based ligands
info:eu-repo/semantics/article
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URL
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https://riubu.ubu.es/bitstream/10259/4885/3/Vaquero-Chemistry_2018.pdf.txt
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Vaquero-Chemistry_2018.pdf.txt