2026-05-14T14:15:26Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/48852026-02-06T12:54:43Zcom_10259_4365com_10259_5086com_10259_2604com_10259_4363col_10259_4366col_10259_4364

Vaquero Gutiérrez, Mónica 569 500 0000-0002-4550-4072 Ruiz Riaguas, Alba a403332f-70fe-43c9-857f-777581960603 500 Martínez Alonso, Marta 772 500 0000-0002-0931-5274 Jalón Sotés, Félix Ángel 83a58ec8-3904-4c18-838c-bcdaf7357757 600 Manzano, Blanca R. . 0f83ceaf-9369-470a-a22b-9b5894978fc0 500 Rodríguez, Ana M. . 64013be0-a1f8-4eba-8154-e6f7c49a9c55 500 García Herbosa, Gabriel 205 500 0000-0002-2863-1272 Carbayo Martín, Mª Aránzazu 99 500 0000-0003-4738-4323 García Ruiz, Begoña 217 500 0000-0002-0817-1651 Espino Ordóñez, Gustavo 162 500 0000-0001-5617-5705 2018-08-27T08:18:09Z 2019-07-25T02:45:07Z 2018-07 0947-6539 http://hdl.handle.net/10259/4885 10.1002/chem.201801173 A new family of heteroleptic bis-cyclometalated IrIII complexes with formula [Ir(C _ N)2(N _ N)]Cl (C _ N=2-phenylpyridinate and N _ N=2,2’-dipyridylamine or N-benzylated 2,2’-dipyridylamines, were synthesized, characterized, and successfully used as photosensitizers in the catalytic photooxidation of an array of dialkyl, dibenzyl, alkyl aryl, and diaryl sulfides, as well as sulfur-containing amino acids. Furthermore, the reactions proceeded with optimal chemoselectivity, and atom economy under mild conditions. Experimental observations support a dual mechanism in which singlet oxygen and superoxide are the actual oxidants. Consejer &a de Educacijn-Junta de Castilla y Lejn (BU042U16). Financial support by the Spanish Ministry of Economy and Competitiveness (MINECO) (projects CTQ2014-58812-C2@1-R, (CTQ2014-58812-C2-2-R, CTQ2015-70371-REDT, FEDER funds), Obra Social “la Caixa” (OSLC-2012-007), Junta de Castilla y Lejn (BU-042U16) application/pdf eng Wiley-VCH Verlag Chemistry-a european journal. 2018, V. 24, n. 42, p. 10662-10671 https://doi.org/10.1002/chem.201801173 info:eu-repo/grantAgreement/JCyL/BU042U16 info:eu-repo/grantAgreement/MINECO/CTQ2014-58812-C2-1-R info:eu-repo/grantAgreement/MINECO/CTQ2014-58812-C2-2-R info:eu-repo/grantAgreement/MINECO/CTQ2015-70371-REDT info:eu-repo/grantAgreement/FundaciónLaCaixa/OSLC-2012-007 Química Chemistry Selective photooxidation of sulfides catalyzed by bis‐cyclometalated IrIII photosensitizers bearing 2,2′‐dipyridylamine‐based ligands info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion info:eu-repo/semantics/openAccess THUMBNAIL Vaquero-Chemistry_2018.pdf.jpg Vaquero-Chemistry_2018.pdf.jpg IM Thumbnail image/jpeg 3661 https://riubu.ubu.es/bitstream/10259/4885/4/Vaquero-Chemistry_2018.pdf.jpg 3e63e424987b5bc20bf409cbdda4b2ef MD5 4 ORIGINAL Vaquero-Chemistry_2018.pdf Vaquero-Chemistry_2018.pdf application/pdf 1450521 https://riubu.ubu.es/bitstream/10259/4885/1/Vaquero-Chemistry_2018.pdf 9fbc188524dbf24c450b4ac5f516c812 MD5 1 LICENSE license.txt license.txt text/plain; charset=utf-8 999 https://riubu.ubu.es/bitstream/10259/4885/2/license.txt b295bcbce42e2caabeb0c623d3860c06 MD5 2 TEXT Vaquero-Chemistry_2018.pdf.txt Vaquero-Chemistry_2018.pdf.txt Extracted text text/plain 53386 https://riubu.ubu.es/bitstream/10259/4885/3/Vaquero-Chemistry_2018.pdf.txt 5e2db665fd332f9c6825d391f65e7a47 MD5 3 10259/4885 oai:riubu.ubu.es:10259/4885 2026-02-06 13:54:43.154 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es 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