2026-04-29T04:14:13Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/49202021-11-10T09:38:25Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Virumbrales, Cintia
578
500
0000-0003-0211-8988
Suarez Pantiga, Samuel
544
500
Solas Luera, Marta
542
500
Fernández Rodríguez, Manuel A.
174
500
Sanz Díez, Roberto
531
500
2018-09-07T08:21:18Z
2019-04-21T02:45:07Z
2018-04
1477-0520
http://hdl.handle.net/10259/4920
10.1039/c8ob00406d
The gold(I)-catalyzed oxycyclization of β-aryl monosubstituted
o-(alkynyl)styrenes gives rise to 1-α-methoxy or 1-α-hydroxybenzyl-
1H-indenes in a diastereospecific way. In contrast to
β,β-disubstituted o-(alkynyl)styrenes, the stereochemical outcome
of this process, diastereospecific reaction supports the higher contribution
of a gold intermediate with a cyclopropylcarbene-like
character.
Ministerio de Economía y
Competitividad (MINECO) and FEDER (CTQ2016-75023-C2-1-
P), and Junta de Castilla y León and FEDER (BU076U16)
application/pdf
eng
Royal Society of Chemistry
Organic & Biomolecular Chemistry. 2018, V. 16, n. 15, p. 2623-2628
https://doi.org/10.1039/c8ob00406d
info:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P
info:eu-repo/grantAgreement/JCyL/BU076U16
Química orgánica
Chemistry, Organic
Gold(I)-catalyzed diastereoselective synthesis of 1-α-oxybenzyl-1H-indenes
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
info:eu-repo/semantics/openAccess
THUMBNAIL
Virumbrales-obc_2018.pdf.jpg
Virumbrales-obc_2018.pdf.jpg
IM Thumbnail
image/jpeg
5194
https://riubu.ubu.es/bitstream/10259/4920/4/Virumbrales-obc_2018.pdf.jpg
aa92f6b4100bbf4ee49a23b9ad3e8a72
MD5
4
ORIGINAL
Virumbrales-obc_2018.pdf
Virumbrales-obc_2018.pdf
application/pdf
698084
https://riubu.ubu.es/bitstream/10259/4920/1/Virumbrales-obc_2018.pdf
5c055398e5dbaa765a3bd86e45856b56
MD5
1
LICENSE
license.txt
license.txt
text/plain; charset=utf-8
999
https://riubu.ubu.es/bitstream/10259/4920/2/license.txt
b295bcbce42e2caabeb0c623d3860c06
MD5
2
TEXT
Virumbrales-obc_2018.pdf.txt
Virumbrales-obc_2018.pdf.txt
Extracted text
text/plain
39881
https://riubu.ubu.es/bitstream/10259/4920/3/Virumbrales-obc_2018.pdf.txt
49d10ba31c2ff95f72ed62dd0b98988e
MD5
3
10259/4920
oai:riubu.ubu.es:10259/4920
2021-11-10 10:38:25.132
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
RWwgYXV0b3IgY29tbyDDum5pY28gdGl0dWxhciBkZSBsb3MgZGVyZWNob3MgZGUgcHJvcGllZGFkIGludGVsZWN0dWFsIGRlIGxhIG9icmEsIG8gZGlzcG9uaWVuZG8gZGUgbG9zIGRlYmlkb3MgcGVybWlzb3MgZGUgbG9zIG90cm9zIHRpdHVsYXJlcywgc2kgbG9zIGh1YmllcmEsIHkgZW4gdmlydHVkIGRlIGxvcyBkZXJlY2hvcyBxdWUgbGUgY29uZmllcmUgbGEgbGVnaXNsYWNpw7NuIHZpZ2VudGUgc29icmUgcHJvcGllZGFkIGludGVsZWN0dWFsIHkgZGVyZWNob3MgZGUgYXV0b3IsIA0KQVVUT1JJWkEgYSBsYSBVbml2ZXJzaWRhZCBkZSBCdXJnb3MgYSBkaWZ1bmRpciwgZGUgbWFuZXJhIGdyYXR1aXRhLCBlbCBjb250ZW5pZG8gZGUgbG9zIGFyY2hpdm9zIGRpZ2l0YWxlcyBxdWUgY29ycmVzcG9uZGVuIGFsIGRvY3VtZW50byBkZXNjcml0byBhbnRlcmlvcm1lbnRlLCBjb24gY2Fyw6FjdGVyIG5vIGV4Y2x1c2l2byB5IGRlIG1hbmVyYSBww7pibGljYSBlbiBhY2Nlc28gYWJpZXJ0byBhIHRyYXbDqXMgZGUgSW50ZXJuZXQsIHBhcmEgbG8gcXVlIGxhIEJpYmxpb3RlY2EgcHJvY2VkZXLDoSBhIGFyY2hpdmFybG9zIGVuIGVsIFJlcG9zaXRvcmlvIEluc3RpdHVjaW9uYWwuIEFzaW1pc21vIGF1dG9yaXphIGEgbGEgVW5pdmVyc2lkYWQgZGUgQnVyZ29zIGEgcmVhbGl6YXIgbGFzIHRyYW5zZm9ybWFjaW9uZXMgbmVjZXNhcmlhcyBkZSBmb3JtYXRvLCBubyBkZSBjb250ZW5pZG8sIHBhcmEgZ2FyYW50aXphciBsYSBwcmVzZXJ2YWNpw7NuIHkgZWwgYWNjZXNvIGVuIGVsIGZ1dHVyby4NCg0KRWwgYXV0b3IgZGlzcG9uZSwgZW4gdG9kbyBjYXNvLCBkZWwgZGVyZWNobyBhIHJldm9jYXIgZXN0YSBhdXRvcml6YWNpw7NuLg0KDQpMYSBjZXNpw7NuIGRlIGRlcmVjaG9zIGRlIGVzdGEgb2JyYSBzZSBlbmN1ZW50cmEgc3VqZXRhIGEgbGEgbGVnaXNsYWNpw7NuIHZpZ2VudGUgc29icmUgcHJvcGllZGFkIGludGVsZWN0dWFsIHkgZGVyZWNob3MgZGUgYXV0b3Iu