2026-04-22T20:18:26Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/49312024-07-24T11:40:18Zcom_10259_9476com_10259.4_106com_10259_2604col_10259_9477

00925njm 22002777a 4500 dc Milanese, Chiara . author Garroni, Sebastiano author Gennari, Fabiana C. author Marini, Amedeo . author Klassen, Thomas . author Dornheim, Martin . author Pistidda, Claudio . author 2018-08 The safest way to store hydrogen is in solid form, physically entrapped in molecular form in highly porous materials, or chemically bound in atomic form in hydrides. Among the different families of these compounds, alkaline and alkaline earth metals alumino-hydrides (alanates) have been regarded as promising storing media and have been extensively studied since 1997, when Bogdanovic and Schwickardi reported that Ti-doped sodium alanate could be reversibly dehydrogenated under moderate conditions. In this review, the preparative methods; the crystal structure; the physico-chemical and hydrogen absorption-desorption properties of the alanates of Li, Na, K, Ca, Mg, Y, Eu, and Sr; and of some of the most interesting multi-cation alanates will be summarized and discussed. The most promising alanate-based reactive hydride composite (RHC) systems developed in the last few years will also be described and commented on concerning their hydrogen absorption and desorption performance 2075-4701 http://hdl.handle.net/10259/4931 10.3390/met8080567 alanates metal aluminum hydrides solid state hydrogen storage complex hydrides reactive hydride composite Solid state hydrogen storage in alanates and alanate-based compounds: a review