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oai:riubu.ubu.es:10259/58102021-11-02T12:06:46Zcom_10259_5822com_10259_5086com_10259_2604col_10259_5823

Ventosa Arbaizar, Edgar a657ff78-9d9c-4d24-aac4-c4adbaac9992 500 2021-06-21T08:38:04Z 2021-06-21T08:38:04Z 2021-02 2451-9103 http://hdl.handle.net/10259/5810 10.1016/j.coelec.2020.09.002 The active materials constitute the heart of any battery so that unambiguous determination of their intrinsic properties is of essential importance to achieve progress in battery research. A variety of in situ techniques with high lateral resolution has been developed or adapted for battery research. Surprisingly, nanoelectrochemistry is not attracting sufficient attention from the battery community despite the existing examples of relevant in situ and highly resolved spatiotemporal information. Herein, the important role of nanoelectrochemistry in battery research is highlighted to help encourage its use in this field. In the first part, two examples in which the use of nanoelectrochemistry is a must are provided, that is, determination of intrinsic kinetics of active materials and understanding of relationships between particle structure and electrochemical activity. In the second part, pros and cons of three mature nanoelectrochemistry techniques in battery research, that is, particle-on-a-stick measurements, nanoimpact measurements, and scanning electrochemical probe microscopy, are discussed providing representative examples. Spanish Government (MINECO) through the Research Challenges Programme (grant RTI2018-099228-A-I00) and Ramón y Cajal award (RYC2018-026086-I) as well as the NanoBat project. NanoBat has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement no. 861962. application/pdf eng Elsevier Current Opinion in Electrochemistry. 2021, V. 25, 100635 https://doi.org/10.1016/j.coelec.2020.09.002 info:eu-repo/grantAgreement/MINECO/ RTI2018-099228-A-I00 info:eu-repo/grantAgreement/MINECO/RYC2018-026086-I) info:eu-repo/grantAgreement/EC/H2020/861962 Atribución 4.0 Internacional http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Electrochemical energy storage Battery Active material Nanoelectrochemistry Single entity Química analítica Chemistry, Analytic Why nanoelectrochemistry is necessary in battery research? info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Current Opinion in Electrochemistry 25 100635 ORIGINAL Ventosa-coe_2021.pdf Ventosa-coe_2021.pdf application/pdf 778769 https://riubu.ubu.es/bitstream/10259/5810/1/Ventosa-coe_2021.pdf 6652d7a0bc0f98c4c86b66270d319cd9 MD5 1 CC-LICENSE license_rdf license_rdf application/rdf+xml; charset=utf-8 908 https://riubu.ubu.es/bitstream/10259/5810/2/license_rdf 0175ea4a2d4caec4bbcc37e300941108 MD5 2 LICENSE license.txt license.txt text/plain; charset=utf-8 999 https://riubu.ubu.es/bitstream/10259/5810/3/license.txt b295bcbce42e2caabeb0c623d3860c06 MD5 3 THUMBNAIL Ventosa-coe_2021.pdf.jpg Ventosa-coe_2021.pdf.jpg IM Thumbnail image/jpeg 3875 https://riubu.ubu.es/bitstream/10259/5810/4/Ventosa-coe_2021.pdf.jpg 7fecd0e95cc7d6ba0dbd5a7c9293ac83 MD5 4 10259/5810 oai:riubu.ubu.es:10259/5810 2021-11-02 13:06:46.296 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es 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