2026-04-17T05:08:59Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/60882022-11-08T13:31:41Zcom_10259_4244com_10259_5086com_10259_2604col_10259_4245

Benito Román, Oscar Blanco Alcalde, Beatriz Sanz Díez, Mª Teresa Beltrán Calvo, Sagrario 2021-11-04T09:22:56Z 2021-11-04T09:22:56Z 2020-12 2076-3921 http://hdl.handle.net/10259/6088 10.3390/antiox9121233 The valorization of onion skin wastes (OSW) through the extraction, identification, and quantification of phenolic compounds was studied in this work, using subcritical water in a semicontinuous extractor (2.5 mL/min; 105–180 C; 5 MPa). The extraction of flavonoids resulted to be fast (<30 min) and temperature sensitive (maximum at 145 C; total flavonoids, 27.4 0.9 mg/g dry OSW (DOSW)). The experimental results were fitted to theWeibull model. The influence of the solvent properties on the flavonoids quantification was found to be critical. A precipitate was formed once the extracts cooled down. If removed, a significant fraction of the high temperature extracted flavonoids (as much as 71%, at 180 C) was lost. Such a condition a ected especially those compounds that show extremely low solubility in water at room temperature, whereas quercetin glycosylated derivatives were less a ected by the polarity change of the medium induced by the temperature change. It was demonstrated that it is necessary to re-dissolve the subcritical water extracts by the addition of ethanol, which led to a medium with a polarity equivalent to that obtained with water at high temperature. At 145 C, quercetin (15.4 0.4 mg/g DOSW) and quercetin-40-glucoside (8.4 0.1 mg/g DOSW) accounted for the 90% of the total flavonoids identified. By recovering high added value bioactive compounds from OSW the principles of circular economy were fulfilled, providing a new use for this agricultural waste. Junta de Castilla y León (JCyL) and the European Regional Development Fund (ERDF)) through projects BU301P18 and BU050P20, and by the Agencia Estatal de Investigación through grant number PID2019-104950RB-I00/AEI/10.13039/501100011033. OBR’s postdoctoral contract was funded by JCyL and EDRF through project BU301P18. application/pdf eng MDPI Antioxidants. 2020, V. 9, n. 12, 1233 https://doi.org/10.3390/antiox9121233 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104950RB-I00/ES/VALORIZACION DE SUBPRODUCTOS MARINOS MEDIANTE TECNOLOGIAS DE FLUIDOS SUB- Y SUPERCRITICOS PARA LA OBTENCION DE BIOCOMPUESTOS VALIOSOS info:eu-repo/grantAgreement/Junta de Castilla y León//BU301P18 info:eu-repo/grantAgreement/Junta de Castilla y León//BU050P20 Atribución 4.0 Internacional http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Onion Extraction Subcritical water Quercetin Polarity Valorization Ingeniería química Chemical engineering Subcritical water extraction of phenolic compounds from onion skin wastes (Allium cepa cv. horcal): effect of temperature and solvent properties info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Antioxidants