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oai:riubu.ubu.es:10259/61222022-11-15T12:55:38Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

Garoz Ruiz, Jesús Perales Rondon, Juan Víctor Heras Vidaurre, Aránzazu Colina Santamaría, Álvaro 2021-11-08T12:22:14Z 2021-11-08T12:22:14Z 2019-07 1040-0397 http://hdl.handle.net/10259/6122 10.1002/elan.201900075 1521-4109 Spectroelectrochemistry (SEC) has been used for more than 50 years, but this set of techniques has not been widely used for quantitative analysis. For many years, no commercial instruments were available, which made very difficult to spread the use of SEC. Nowadays, only the creativity of the researchers is required to exploit the capabilities of SEC. This review is written with the aim of showing the potential of SEC, mainly for analytical chemistry. Here, we explain what SEC is, how analytical responses can be obtained, why these techniques are useful for sensors, with a brief description of its advantages in use, and, finally, we try to show the challenges that must be addressed in the next years. SEC can resolve interesting analytical problems using the high amount of data provided by this intrinsic trilinear technique. Given the quantitative analysis point of view of this review, the discussion of the SEC techniques is focused on UV/Vis absorption, photoluminescence and Raman SEC. Spectroelectrochemistry (SEC) has been used for more than 50 years, but this set of techniques has not been widely used for quantitative analysis. For many years, no commercial instruments were available, which made very difficult to spread the use of SEC. Nowadays, only the creativity of the researchers is required to exploit the capabilities of SEC. This review is written with the aim of showing the potential of SEC, mainly for analytical chemistry. Here, we explain what SEC is, how analytical responses can be obtained, why these techniques are useful for sensors, with a brief description of its advantages in use, and, finally, we try to show the challenges that must be addressed in the next years. SEC can resolve interesting analytical problems using the high amount of data provided by this intrinsic trilinear technique. Given the quantitative analysis point of view of this review, the discussion of the SEC techniques is focused on UV/Vis absorption, photoluminescence and Raman SEC. Ministerio de Economía y Competitividad (Grants CTQ2017-83935-R-AEI/FEDERUE) and Junta de Castilla y León (Grant BU033-U16 and BU297P18). J. G.–R. thanks UBU for his postdoctoral contract. J.V.P–R. thanks JCyL for his postdoctoral fellowship (Grant BU033-U16). Thanks to J application/pdf spa Wiley Electroanalysis. 2019, V.31, n. 7, p. 1254–1278 https://doi.org/10.1002/elan.201900075 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-83935-R/ES/ESPECTROELECTROQUIMICA RAMAN CUANTITATIVA info:eu-repo/grantAgreement/Junta de Castilla y León//BU033-U16//Desarrollo de un equipo compacto de espectroelectroquímica Raman info:eu-repo/grantAgreement/Junta de Castilla y León//BU297P18 Spectroelectrochemistry Sensors UV/Vis absorption Photoluminescence Raman Química analítica Chemistry, Analytic Spectroelectrochemical Sensing: Current Trends and Challenges info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion info:eu-repo/semantics/openAccess