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oai:riubu.ubu.es:10259/61252022-11-15T13:30:15Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

Chemical selectivity in electrochemical surface oxidation enhanced Raman scattering Pérez Estébanez, Martín Hernández Muñoz, Sheila Perales Rondon, Juan Víctor Gomez, Elvira Heras Vidaurre, Aránzazu Colina Santamaría, Álvaro Spectroelectrochemistry Raman SERS EC-SOERS Silver roughening Química analítica Chemistry, Analytic Electrochemical Surface Oxidation Enhanced Raman Scattering (EC-SOERS) is an interesting and promising phenomenon capable of amplifying the Raman signal in a similar way to Surface Enhanced Raman Scattering (SERS), but EC-SOERS takes place during the oxidation of a silver substrate. This phenomenon was originally described for specific electrolytic conditions in which a small amount of chloride in acidic medium was mandatory to obtain a substantial enhancement. Herein, we demonstrate that EC-SOERS can be also observed in presence of KBr, showing a potential-dependent behavior. Moreover, in this work a novel approach to reach chemical selectivity during time resolved Raman spectroelectrochemistry (TR-Raman-SEC) experiments is proposed. This new approach is based on the effect of the electrolytic medium on the structures that are formed on the electrode surface. SEM studies were carried out to study the origin of this selectivity. Although SEM images reveal clear differences between the structures of silver halides formed on the electrode surface during the oxidation of the substrate, the absence of EC-SOERS effect at open circuit potential hinders the identification of the actual structures responsible for the phenomenon. Ministerio de Economía y Competitividad (Grants CTQ2017-83935-R-AEI/FEDERUE), Junta de Castilla y León (BU297P18) and Ministerio de Ciencia, Innovación y Universidades (RED2018-102412-T) 2021-11-08T13:37:04Z 2021-11-08T13:37:04Z 2020-09 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion 0013-4686 http://hdl.handle.net/10259/6125 10.1016/j.electacta.2020.136560 spa Electrochimica Acta. 2020, V. 353, 136560 https://doi.org/10.1016/j.electacta.2020.136560 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-83935-R/ES/ESPECTROELECTROQUIMICA RAMAN CUANTITATIVA info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/ RED2018-102412-T/ES/RED DE SENSORES Y BIOSENSORES ELECTROQUIMICOS info:eu-repo/grantAgreement/Junta de Castilla y León//BU297P18 info:eu-repo/semantics/openAccess application/pdf Elsevier https://riubu.ubu.es/bitstream/10259/6125/3/Perez-ea_2020.pdf.jpg Hispana TEXT http://rightsstatements.org/vocab/CNE/1.0/ RIUBU. Repositorio Institucional de la Universidad de Burgos http://hdl.handle.net/10259/6125