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<mods:namePart>Verbeeten, Wilco M.H.</mods:namePart>
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<mods:namePart>Lorenzo Bañuelos, Miriam</mods:namePart>
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<mods:dateAccessioned encoding="iso8601">2022-08-30T08:04:45Z</mods:dateAccessioned>
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<mods:identifier type="uri">http://hdl.handle.net/10259/6821</mods:identifier>
<mods:identifier type="doi">10.1016/j.addma.2022.103079</mods:identifier>
<mods:abstract>The effect that the infill orientation angle has on the strain-rate dependence of the yield stress for material&#xd;
extrusion additive manufactured (ME-AM) PolyLactic Acid (PLA) material was investigated. Symmetric angleply stacking sequences were used to produce ME-AM tensile test samples. Measured yield stresses were&#xd;
compensated for the voided structure, typical of ME-AM components. Furthermore, molecular orientation and&#xd;
stretch was macroscopically assessed by a thermal shrinkage procedure. Additionally, hot-press compression&#xd;
molded (CM) samples were manufactured and mechanically characterized in uniaxial tensile and compression&#xd;
in order to determine the material’s isotropic bulk properties. Initial model parameters for the Ree–Eyring&#xd;
modification of the Eyring flow rule were determined using CM data. According to SEM fractography, all&#xd;
samples showed microscopically brittle fracture behavior. Notwithstanding, contrary to CM samples, ME-AM&#xd;
specimens showed macroscopically ductile stress–strain behavior and a transition from a regime with only&#xd;
a primary 𝛼-deformation process, at low strain rates, to a regime with 2 deformation processes (𝛼 + 𝛽), at&#xd;
high strain rates. These effects are an influence of the processing step and are attributed to the molecular&#xd;
orientation and stretch of the polymer chains, provoking anisotropic mechanical properties. As a consequence,&#xd;
a deformation-induced change of the Eyring rate constants is needed to adequately describe the strain-rate&#xd;
dependence of the ME-AM yield stress behavior, leaving the initial activation volumes unchanged. Taking this&#xd;
deformation-dependence of the rate constants into account, yield stresses as a function of infill orientation&#xd;
angle can be appropriately predicted.</mods:abstract>
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<mods:accessCondition type="useAndReproduction">Attribution-NonCommercial-NoDerivatives 4.0 Internacional</mods:accessCondition>
<mods:subject>
<mods:topic>PLA</mods:topic>
</mods:subject>
<mods:subject>
<mods:topic>Angle-ply laminate configuration</mods:topic>
</mods:subject>
<mods:subject>
<mods:topic>Anisotropic strain-rate dependent yield stress</mods:topic>
</mods:subject>
<mods:subject>
<mods:topic>Ree–Eyring rate equation</mods:topic>
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<mods:titleInfo>
<mods:title>Material Extrusion Additive Manufacturing of Poly(Lactic Acid): Influence of infill orientation angle</mods:title>
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