2026-04-18T07:59:46Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/74802023-04-17T11:22:49Zcom_10259_3844com_10259_5086com_10259_2604com_10259_3843com_10259_3591com_10259.4_106col_10259_3845col_10259_6162
Hernández Muñoz, Sheila
275
600
0000-0002-0466-8759
García, Lydia
4f326836-02d9-4fbc-bffb-41dcaeda28b6
600
Pérez Estébanez, Martín
777
600
0000-0003-1510-5422
Cheuquepan Valenzuela, William
764
600
0000-0001-6741-1144
Heras Vidaurre, Aránzazu
273
600
0000-0002-5068-2164
Colina Santamaría, Álvaro
122
600
0000-0003-0339-356X
2023-03-01T13:21:11Z
2023-03-01T13:21:11Z
2022-08
1572-6657
http://hdl.handle.net/10259/7480
10.1016/j.jelechem.2022.116478
A new, simple and fast protocol to generate gold-based SERS substrates is presented in this work. Melamine is a
compound widely used in the industry that can be toxic for humans if consumed even in low concentrations.
EC-SERS is an excellent alternative to classical methods to detect and quantify this compound because Raman
spectroscopy provides a fingerprint of the molecules, providing very good sensitivity. In this work, timeresolved Raman spectroelectrochemistry is employed to generate a SERS substrate and to detect melamine,
all in a single experiment. The dynamic character of this technique provides valuable information about the
interaction of the molecule with the generated substrate. An optimization of the spectroelectrochemical
method based on a multi-pulse amperometric detection has been performed. The new protocol presented in
this work shows significant figures of merit in a very short experiment time, just 25 s.
Authors acknowledge the financial support from Agencia Estatal de Investigación/Ministerio de Ciencia e Innovacion /10.13039/ 501100011033 (Grant PID2020-113154RB-C21) and Ministerio de Ciencia, Innovación y Universidades (Grant RED2018-102412-T). W. Ch. thanks JCyL for his postdoctoral fellowship (Grant BU297P18). S.H. and M.P-E. thank JCyL and European Social Fund for their predoctoral fellowships.
eng
Elsevier
Journal of Electroanalytical Chemistry. 2022, V. 918, 116478
https://doi.org/10.1016/j.jelechem.2022.116478
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113154RB-C21/ES/APLICACION DE NUEVOS MATERIALES Y DISPOSITIVOS PARA EC-SERS Y EC-SOERS/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RED2018-102412-T/ES/RED DE SENSORES Y BIOSENSORES ELECTROQUIMICOS/
info:eu-repo/grantAgreement/Junta de Castilla y León//BU297P18//Fusión de técnicas espectroelectroquímicas avanzadas/
Atribución 4.0 Internacional
http://creativecommons.org/licenses/by/4.0/
info:eu-repo/semantics/openAccess
EC-SERS
Gold-electrodes
Time-resolved spectroelectrochemistry
Raman
Melamine
Química analítica
Chemistry, Analytic
Multiamperometric-SERS detection of melamine on gold screen-printed electrodes
info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Journal of Electroanalytical Chemistry
918
THUMBNAIL
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oai:riubu.ubu.es:10259/7480
2023-04-17 13:22:49.544
Repositorio Institucional de la Universidad de Burgos
bubrep@ubu.es
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