2026-04-19T07:55:13Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/82272023-12-20T11:35:11Zcom_10259_4365com_10259_5086com_10259_2604com_10259_7463col_10259_4366col_10259_7464
Repositorio Institucional de la Universidad de Burgos
author
Navarro Cuñado, A. Marta
author
García Ruiz, Begoña
author
Hoyuelos Álvaro, Fco. Javier
author
Peñacoba Maestre, Indalecio A.
author
Ibeas Cortes, Saturnino
author
Leal Villalba, José María
2023-12-20T11:28:41Z
2023-12-20T11:28:41Z
2012-08
1520-6106
http://hdl.handle.net/10259/8227
10.1021/jp302934b
1520-5207
Heat capacities for the binary mixtures of methanol with (C1–C4) alkylbenzoates and methylbenzoate with (C1–C11) alkan-1-ols have been measured over the whole composition range at 298.15 K under atmospheric pressure. From the experimental measurements, the derived excess molar heat capacities and partial excess molar heat capacities at infinite dilution have been calculated. A Redlich–Kister-type equation was fitted to these data, and the fitting parameters and standard deviations have been evaluated. Likewise, the IR spectra for the same systems have been recorded as a function of composition. The sets of experimental data gathered contribute to shed light onto the solvent structure and the underlying molecular interactions between the mixture constituents. The conclusions drawn have been established in terms of solute–solvent and solvent–solvent interactions and the ensuing structural effects between the solvent constituents.
eng
Alcohols
Heat capacity
Mixtures
Organic compounds
Solvents
Heat Capacity Behavior and Structure of Alkan-1-ol/Alkylbenzoate Binary Solvents
info:eu-repo/semantics/article
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URL
https://riubu.ubu.es/bitstream/10259/8227/1/Navarro-jpcb_2012.doc
File
MD5
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application/msword
Navarro-jpcb_2012.doc