2026-04-17T10:26:20Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/84592024-01-25T01:05:25Zcom_10259_4354com_10259_5086com_10259_2604com_10259_4363com_10259_4313com_10259_3592com_10259_3591com_10259.4_106col_10259_4355col_10259_4364col_10259_4314col_10259_3930

García Calvo, José Calvo Gredilla, Patricia Vallejos Calzada, Saúl García Pérez, José Miguel Cuevas Vicario, José Vicente García Herbosa, Gabriel Avella, Manuel Torroba Pérez, Tomás 2024-01-24T12:51:39Z 2024-01-24T12:51:39Z 2018-07 1463-9270 http://hdl.handle.net/10259/8459 10.1039/C8GC01522H 1463-9262 The preparation of new monodisperse polycrystalline palladium nanoparticles uniformly distributed on the surface of polymers, by simply adding a palladium(II) solution in water to the polymers, is described. The polymer supported palladium nanoparticles material was used as an efficient portable and reusable catalyst for the stereoselective semihydrogenation reaction of internal alkynes to (Z)-alkenes in green solvents. We gratefully acknowledge financial support from the Ministerio de Economía y Competitividad, Spain, and Fondo Europeo de Desarrollo Regional (FEDER) (Projects CTQ2015-71353-R and MAT2017-84501-R) and Junta de Castilla y León, Consejería de Educación y Cultura y Fondo Social Europeo (Projects BU051U16 and BU061U16). This research has made use of the high performance computing resources of the Castilla y León Supercomputing Center (SCAYLE, https://www.scayle.es), financed by the European Regional Development Fund (ERDF). J. G.-C. thanks Ministerio de Economía y Competitividad for his predoctoral FPU fellowship. This paper is dedicated to the memory of the late Dr Stefano Marcaccini. application/pdf eng Royal Society of Chemistry Green Chemistry. 2018, V. 20, n. 16, p. 3875-3883 https://doi.org/10.1039/C8GC01522H Química orgánica Chemistry, Organic Palladium nanodendrites uniformly deposited on the surface of polymers as an efficient and recyclable catalyst for direct drug modification via Z-selective semihydrogenation of alkynes info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion info:eu-repo/semantics/openAccess Green Chemistry 20 16 3875 3883