ANEXO I: This readme.txt file was generated on 2023-03-14 by Saul Vallejos Calzada GENERAL INFORMATION 1. Title of dataset: Dataset of the work "Metal-free organocatalysts for high hydrolytic stability single component polyurethane adhesives and their application in decorative insulation facades manufacturing" 2. Autorship Name: Saul Vallejos Calzada Institution: Departamento de Química. Universidad de Burgos Email: svallejos@ubu.es ORCID: https://orcid.org/0000-0001-5522-6574 Name: Miriam Trigo Lopez Institution: Departamento de Química. Universidad de Burgos Email: mtrigo@ubu.es ORCID: https://orcid.org/0000-0001-5948-1230 Name: Haritz Sardon Institution: POLYMAT. Universidad del País Vasco Email: haritz.sardon@ehu.eus ORCID: https://orcid.org/0000-0002-6268-0916 Name: José Manuel González Martín Institution: Departamento de Construcciones Arquitectónicas e Ingeniería de la Construcción y del Terreno. Universidad de Burgos Email: jmgonza@ubu.es ORCID: https://orcid.org/0000-0003-2593-3192 Name: José Miguel García Pérez Institution: Departamento de Química. Universidad de Burgos Email: svallejos@ubu.es ORCID: https://orcid.org/0000-0002-2674-8194 DESCRIPTION ----------- 1. Dataset language English 2. Abstract: The dataset contains all raw data of the work "Metal-free organocatalysts for high hydrolytic stability single component polyurethane adhesives and their application in decorative insulation facades manufacturing" 3. Keywords: Single-component polyurethane adhesive; metal-free catalyst; colorimetry; RGB parameters; home-made system; DBU; naphthoic acid; fan. 4. Date of data collection 2022-2023 5. Date of dataset publication 2023-03-14 6. Funding We gratefully acknowledge the financial support provided by all funders. This work was supported by the Regional Government of Castilla y León (Junta de Castilla y León) and by the Ministry of Science and Innovation MICIN and the European Union NextGenerationEU PRTR. Author Jose Miguel García received grant PID2020-113264RB-I00 funded by MCIN/AEI/ 10.13039/501100011033 and by “ERDF A way of making Europe”. 7. Geographic location/s of data collection Burgos (Spain) ACCESS INFORMATION ------------------ 1. Dataset Creative Commons License: CC 4.0 Internacional 2. Dataset DOI: XXXXXXXXXXXXXXXXXXX 3. Related publication The related article has been sent to: ACS Applied Materials & Interfaces METHODOLOGICAL INFORMATION -------------------------- Viscosity data was obtained using a Brookfield viscometer (Model RVDV-II+, LR99102), at 100 RPM, spin number 04, and 30ºC. To obtain the isocyanate index (% NCO) of the adhesives, the standard D2572 − 97 (2010) of the ASTM committee entitled "Standard Test Method for Isocyanate Groups in Urethane Materials or Prepolymers" was followed. 1H and 13C{1H} NMR spectra (Advance III HD spectrometer, Bruker Corporation, Billerica, Massachusetts, USA) were recorded at 300 MHz for 1H and 75 MHz for 13C using deuterated dimethylsulfoxide (DMSO-d6) at 25°C as solvent. Catalysts #9 and #10, exceptionally, were tested at 50°C for avoiding signals from different the conformational isomers in 13C-NMR specta. The catalysts´ thermal characterization was performed by thermogravimetric analysis (Q50 TGA analyzer, TA Instruments, New Castle, DE, USA) with 3–7 mg of sample under nitrogen atmosphere at 10°C·min−1. The catalysts´ and adhesives´ thermal characterization was performed by differential scanning calorimetry under a nitrogen atmosphere at a heating rate of 15 and 20 °C·min−1, respectively (Q200 DSC analyzer, TA Instruments, New Castle, DE, USA). Catalysts were previously dried in a vacuum oven at 35°C, and the experiment was performed with 10–15 mg of sample. Regarding the PUR adhesives, 4 grams of the prepolymer were weighed, and 26 mg of catalyst dissolved in 150 mL of the solvent specified in Table 1 (manuscript) were added. Finally, 80 mL of water was added, the mixture was homogenized, and the experiment was performed with 10-15 mg of sample. This experiment was used as the basis for the theoretical analysis of the curing kinetics of PUR#1, using the "TA Advantage Specialty Library" software. More information can be found in Figures S1f-S11f. Infrared spectra (FTIR) were recorded with an infrared spectrometer (FT/IR-4200, Jasco, Tokyo, Japan) with an ATR-PRO410-S single reflection accessory. Digital photographs were taken with a Huawei p30 pro (Huawei, Shenzhen, China), placing the films within a homemade lightbox to reproduce always the same lighting conditions. The distance between the object and the smartphone was 13 cm. RGB parameters of digital photographs were extracted using the smartphone app “Colorimetric Titration”. FILE OVERVIEW -------------- 09-PUR+DBTDL-45min.jws 10-PUR+DBTDL-60min.jws 01-PUR-0min.jws 02-PUR-15min.jws 03-PUR-30min.jws 04-PUR-45min.jws 05-PUR-60min.jws 06-PUR+DBTDL-0min.jws 07-PUR+DBTDL-15min.jws 08-PUR+DBTDL-30min.jws TGA_CAT_04.txt TGA_CAT_05.txt TGA_CAT_06.txt TGA_CAT_07.txt TGA_CAT_08.txt TGA_CAT_09.txt TGA_CAT_10.txt TGA_CAT_11.txt TGA_PUR.txt TGA_CAT_01.txt TGA_CAT_02.txt TGA_CAT_03.txt Curing kinetics.csv FTIR-CAT 06.txt FTIR-CAT 07.txt FTIR-CAT 08.txt FTIR-CAT 09.txt FTIR-CAT 10.txt FTIR-CAT 11.txt FTIR_PUR.txt FTIR-CAT 01.txt FTIR-CAT 02.txt FTIR-CAT 03.txt FTIR-CAT 04.txt FTIR-CAT 05.txt 1H_NMR_CAT 02.csv 1H_NMR_CAT 03.csv 1H_NMR_CAT 04.csv 1H_NMR_CAT 05.csv 1H_NMR_CAT 06.csv 1H_NMR_CAT 07.csv 1H_NMR_CAT 08.csv 1H_NMR_CAT 09.csv 1H_NMR_CAT 10.csv 1H_NMR_CAT 11.csv 1H_NMR_PUR.csv 1H_NMR_CAT 01.csv 13C_NMR_CAT 08.csv 13C_NMR_CAT 09.csv 13C_NMR_CAT 10.csv 13C_NMR_CAT 11.csv 13C_NMR_PUR.csv 13C_NMR_CAT 01.csv 13C_NMR_CAT 02.csv 13C_NMR_CAT 03.csv 13C_NMR_CAT 04.csv 13C_NMR_CAT 05.csv 13C_NMR_CAT 06.csv 13C_NMR_CAT 07.csv DSC_PUR 07.txt DSC_PUR 08.txt DSC_PUR 09.txt DSC_PUR 10.txt DSC_PUR 11.txt DSC_PUR 01.txt DSC_PUR 02.txt DSC_PUR 03.txt DSC_PUR 04.txt DSC_PUR 05.txt DSC_PUR 06.txt DSC_CAT_05.txt DSC_CAT_06.txt DSC_CAT_07.txt DSC_CAT_08.txt DSC_CAT_09.txt DSC_CAT_10.txt DSC_CAT_11.txt DSC_CAT_01.txt DSC_CAT_02.txt DSC_CAT_03.txt DSC_CAT_04.txt Short description: Each file is a .ods, .txt, .xy or .csv file of each study/experiment