ANEXO I: This readme.txt file was generated on 2023-06-08 by Saul Vallejos Calzada GENERAL INFORMATION 1. Title of dataset: Dataset of the work "Crafting and Analyzing Multi-Structured Aramid Materials and Their Pyrolytic Transformations: A Comprehensive Exploration" 2. Autorship Name: Miriam Trigo Lopez Institution: Departamento de Química. Universidad de Burgos Email: mtrigo@ubu.es ORCID: https://orcid.org/0000-0001-5948-1230 Name: Alvaro Miguel Ortega Institution: Universidad Autónoma de Madrid Email: alvaro.miguel@ubu.es ORCID: https://orcid.org/0000-0003-3981-5699 Name: José Miguel García Pérez Institution: Departamento de Química. Universidad de Burgos Email: svallejos@ubu.es ORCID: https://orcid.org/0000-0002-2674-8194 Name: Edgar Ventosa Arbaizar Institution: Departamento de Química. Universidad de Burgos Email: eventosa@ubu.es ORCID: https://orcid.org/0000-0002-8993-4285 Name: Virginia Ruiz Institution: Departamento de Química. Universidad de Burgos Email: vrfernandez@ubu.es ORCID: https://orcid.org/0000-0002-0466-0634 Name: Artur JM Valente Institution: Departamento de Quimica. Universidade de Coimbra Email: avalente@ci.uc.pt ORCID: https://orcid.org/0000-0002-4612-7686 Name: Saul Vallejos Calzada Institution: Departamento de Química. Universidad de Burgos Email: svallejos@ubu.es ORCID: https://orcid.org/0000-0001-5522-6574 DESCRIPTION ----------- 1. Dataset language English 2. Abstract: The dataset contains all raw data of the work "Crafting and Analyzing Multi-Structured Aramid Materials and Their Pyrolytic Transformations: A Comprehensive Exploration" 3. Keywords: Pyrolysis, aromatic polyamides, aramids, microporous-materials, Nomex, Kevlar. 4. Date of data collection 2022-2023 5. Date of dataset publication 2023-06-08 6. Funding We gratefully acknowledge the financial support provided by all funders. This work was supported by the Regional Government of Castilla y León (Junta de Castilla y León) and by the Ministry of Science and Innovation MICIN and the European Union NextGenerationEU PRTR. Author Jose Miguel García received grant PID2020-113264RB-I00 funded by MCIN/AEI/ 10.13039/501100011033 and by “ERDF A way of making Europe”. Author Miriam Trigo received grant PID2019-108583RJ-I00 funded by MCIN/AEI/ 10.13039/501100011033. Author Saul Vallejos received grant BG22/00086 funded by Spanish Ministerio de Universidades. 7. Geographic location/s of data collection Burgos (Spain) ACCESS INFORMATION ------------------ 1. Dataset Creative Commons License: CC 4.0 Internacional 2. Dataset DOI: 10.36443/10259/7699 3. Related publication The related article has been sent to: METHODOLOGICAL INFORMATION -------------------------- Pyrolysis was performed with a thermobalance (Q50 TGA analyzer, TA Instruments, New Castle, DE, USA). Infrared spectra (FTIR) of the aramids were recorded with an infrared spectrometer (FT/IR-4200, Jasco, Tokyo, Japan) with an ATR-PRO410-S single reflection accessory. FTIR transmittance spectra of the pyramids were acquired pulverizing the sample and preparing KBr pellets. Scanning electron microscopy (SEM) experiments were carried out using an electron microscope (FEI Quanta 600, FELMI-ZFE, Graz, Austria). Aramids were dried in air, fractured and gold sputtered in vacuum to ensure electrical conductivity. Pyramids were not gold sputtered since they are intrinsically conductive materials. RAMAN spectra were recorded with a confocal AFM-RAMAN model Alpha300R – Alpha300A AFM (WITec, Ulm, Germany) using a laser radiation of 532 nm and 1mW, at magnifications of 100×. The electrical resistance (R) of samples was measured using a Jandel 4-point probe (HL Jandel, UK) connected to a 2401 SourceMeter® unit (SMU) instrument (Keithley, Ohio, USA) The surface bulk resistivity (?b) of samples was calculated using the following equation: pb = 2psR where s is the electrode spacing (0.125 cm). The electrical resistance of graphite and steel samples was measured and considered as references. The powder X-ray diffraction (PXRD) patterns were obtained using a diffractometer (D8 Discover Davinci design, Bruker Corporation, Billerica, Massachusetts, USA) operating at 40 kV, using Cu(Ka) as the radiation source, a scan step size of 0.02°, and a scan step time of 2 s. X-ray photoelectron spectra (XPS) were recorded using a Fisons MT500 spectrometer equipped with a hemispherical electron analyser (CLAM2) and a non-monochromatic Mg Ka X-Ray source operated at 300 W. The samples were fixed on small flat discs supported on an XYZ manipulator placed in the analysis chamber. The residual pressure in this ion-pumped analysis chamber was maintained below 10-9 torr during data acquisition. The spectra were collected at a pass energy of 20 eV, which is typical of high-resolution conditions. Spectra were analyzed using CasaXPS software. The intensities were estimated by calculating the area under each peak after subtraction of the S-shaped background and fitting the experimental curve to a combination of Lorentzian and Gaussian lines of variable proportions. Although specimen charging was observed, it was possible to determine accurate binding energies (BEs) by referencing to the adventitious C1s peak at 285.0 eV. The maximum allowed variation of the binding energy was ±0.2 eV relative to the value specified for peak center. The atomic ratios were computed from the peak intensity ratios and the reported atomic sensitivity factors. FILE OVERVIEW -------------- 01-Dense-m-pyramid.txt 02-Microporous-m-pyramid.txt 03-Porous-m-pyramid.txt 04-Woven fabric-p-pyramid.txt 01-XPS.ods 01-p-aramid.txt 02-p-pyramid.txt 03-m-aramid.txt 04-m-pyramid.txt 01-m-aramid.txt 02-m-pyramid.txt Short description: Each file is a .ods, or .txt file of each study/experiment