ANEXO I: This readme.txt file was generated on 2024-05-09 by Saul Vallejos Calzada GENERAL INFORMATION 1. Title of dataset: Dataset of the work "UBU-Polymers Research Group 27022024" 2. Autorship Name: Gianluca Utzeri Institution: Departamento de Quimica. Universidade de Coimbra Email: gianlucautz@gmail.com ORCID: https://orcid.org/0000-0002-8457-4217 Name: Jose Carlos Guirado Moreno Institution: Departamento de Química. Universidad de Burgos Email: jcguirado@ubu.es ORCID: https://orcid.org/0000-0001-6233-5496 Name: Tânia Firmino Guerra Guerreiro Cova Institution: CQC-IMS, Department of Chemistry, University of Coimbra, Portugal Email: tfirmino@qui.uc.pt ORCID: https://orcid.org/0000-0002-2840-6091 Name: Alberto A.A.C. Pais Institution: CQC-IMS, Department of Chemistry, University of Coimbra, Portugal Email: pais@qui.uc.pt ORCID: https://orcid.org/0000-0002-6725-6460 Name: Luis A. E. Batista de Carvalho Institution: Department of Chemistry, University of Coimbra, Portugal Email: labc@ci.uc.pt ORCID: https://orcid.org/0000-0002-8059-8537 Name: Saturnino Ibeas Cortés Institution: Departamento de Química. Universidad de Burgos Email: sibeas@ubu.es ORCID: https://orcid.org/0000-0003-1831-5943 Name: José Miguel García Pérez Institution: Departamento de Química. Universidad de Burgos Email: svallejos@ubu.es ORCID: https://orcid.org/0000-0002-2674-8194 Name: Artur JM Valente Institution: Departamento de Quimica. Universidade de Coimbra Email: avalente@ci.uc.pt ORCID: https://orcid.org/0000-0002-4612-7686 Name: Saul Vallejos Calzada Institution: Departamento de Química. Universidad de Burgos Email: svallejos@ubu.es ORCID: https://orcid.org/0000-0001-5522-6574 DESCRIPTION ----------- 1. Dataset language English 2. Abstract: The dataset contains all raw data of the work "Reusable and Effective Polyacrylic Membranes for Mecoprop and Bentazon Extraction" 3. Keywords: Pesticide extraction; polyacrylic membranes; mecoprop; bentazon; scorpion tail segments; hydrophobic interactions; transport study. 4. Date of data collection 2022-2023 5. Date of dataset publication 2024-05-09 6. Funding We gratefully acknowledge the financial support provided by all funders. The financial support provided by Fondo Europeo de Desarrollo Regional-European Regional Development Fund (FEDER, ERDF) and Regional Government of Castilla y León -Consejería de Educación, Junta de Castilla y León- (BU025P23) is gratefully acknowledged. This work was supported by the Regional Government of Castilla y León (Junta de Castilla y León) and by the Ministry of Science and Innovation MICIN and the European Union NextGenerationEU PRTR. Author J. M. García received grant PID2020-113264RB-I00 funded by MCIN/AEI/ 10.13039/501100011033 and by “ERDF A way of making Europe”. Author Saul Vallejos received grant BG22/00086 funded by Spanish Ministerio de Universidades. The authors also acknowledge Fundação para a Ciência e a Tecnologia (FCT), the Portuguese Agency for Scientific Research for the financial support through project UIDP/00313/2020. Tania Cova acknowledges the Junior Researcher Grant CEECIND/00915/2018 assigned by FCT. Gianluca Utzeri thanks FCT for the PhD grant SFR/BD/146358/2019. 7. Geographic location/s of data collection Burgos (Spain) and Coimbra (Portugal) ACCESS INFORMATION ------------------ 1. Dataset Creative Commons License: CC 4.0 Internacional 2. Dataset DOI: XXXXXXXXXXXXXXXXXXX 3. Related publication The related article has been sent to: Carbon METHODOLOGICAL INFORMATION -------------------------- The thermal characterization of the polymers was performed by thermogravimetric analysis (Q50 TGA analyzer, TA Instruments, New Castle, DE, USA) under nitrogen atmosphere at 10 °C·min−1, and by differential scanning calorimetry under a nitrogen atmosphere at a heating rate of 20 °C·min−1 (Q200 DSC analyzer, TA Instruments, New Castle, DE, USA), using 10–15 mg of sample for each. The water uptake capacity of the films upon soaking in pure water at 20 ºC until reaching equilibrium (water-swelling percentage, WSP) was obtained from the weight of a dry sample film (ωd) and its water-swollen weight (ωs) using the following expression: WSP = 100 × [(ωs × ωd) / ωd]. Tensile properties analysis, with 5 × 9.44 × 0.103 mm samples tested at 5 mm min−1 (EZ Test Compact Table-Top Universal Tester, Shimadzu Kyoto, Japan). The active surface area (SBET), pore volume and pore size distribution were determined by nitrogen sorption–desorption analysis (ASAP 2000, Micrometrics) for the membrane at 10% of NCO groups before and after washing step in water. Fourier transform infrared spectra (FTIR) of the prepared polymeric membranes with 1%, 5% and 10% of the functional monomer before (MEM1, MEM5 and MEM10, respectively) and after washing step with distilled water (MEM, MEM and MEM, respectively), were recorded with an infrared spectrometer (FT/IR-4200, Jasco, Tokyo, Japan) with an ATR-PRO410-S single reflection accessory, for full characterization of membranes structure. To better understanding the sorbent-sorbate interaction, additional experiments were carried out with MEM10, before and after dipping on BTZ and MCP aqueous solutions at 50 mg L−1. These spectra were acquired in attenuated total reflectance (ATR) mode, in the mid-IR range (400-4000 cm−1), in a Bruker Optics Vertex 70 FTIR spectrometer purged by CO2-free dry air and equipped with a Bruker Platinum ATR single reflection diamond accessory. A Ge on KBr substrate beam splitter and a liquid nitrogen-cooled wide band mercury cadmium telluride (MCT) detector were used. Spectra were averaged over 128 scans at a resolution of 2 cm−1, and the 3-term Blackman-Harris apodization function was applied. The Bruker OPUS–Spectroscopy Software (8.1 version) was used to correct the spectra regarding the wavelength dependence of the penetration depth of the electric field in ATR, using a mean refractive index of 1.25. 1H and 13C{1H} NMR spectra (Advance III HD spectrometer, Bruker Corporation, Billerica, Massachusetts, USA) were recorded at 300 MHz for 1H and 75 MHz for 13C using deuterated dimethyl sulfoxide (DMSO-d6) at 25 °C as solvent. The experimental conditions for the interaction study between the polymer and MCP are deeply depicted in Section 2.7. FILE OVERVIEW -------------- FIGURE 3B.txt FIGURE 3C.txt FIGURE 3D.txt FIGURE 4A.csv FIGURE 4B.txt FIGURE 4C.txt FIGURE 4d.txt FIGURE 6D.txt FIGURE 6E.txt FT-IR INTERACTION WITH PESTICIDES.txt FT-IR.ods ISOTHERM BTZ.ods kinetics.ods MECHANICAL PROPERTIES 1%NCO-NOT WASHED.csv MECHANICAL PROPERTIES 5%NCO-NOT WASHED.csv MECHANICAL PROPERTIES 10%NCO-NOT WASHED.csv NCO 10% - Lavado.ods NCO 10% - Sin Lavar.ods Permeation study.ods raman.txt TGA 1%-NOT WASHED.txt TGA 1%-WASHED.txt TGA 5%-NOT WASHED.txt TGA 5%-WASHED.txt TGA 10%-NOT WASHED.txt TGA 10%-WASHED.txt Calibration BTZ.ods Calibration MCP.ods DSC 1%-lavado.txt DSC 1%-NOT WASHED.txt DSC 5%-NOTWASHED.txt DSC 5%-WASHED.txt DSC 10%-NOTWASHED.txt DSC 10%-WASHED.txt FIGURE 3A.txt Short description: Each file is a .ods, or .txt file of each study/experiment