ANEXO I: This readme.txt file was generated on 2024-06-15 by Miriam Trigo López GENERAL INFORMATION 1. Title of dataset: DUBU-Polymers Research Group 21082024 2. Autorship Name:Álvaro Miguel-Ortega Institution: Universidad Autónoma de Madrid, Calle Francisco Tomás y Valiente 7, Fuencarral-El Pardo, 28049 Madrid, Spain. Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Plaza de Misael Bañuelos s/n, 09001 Burgos, Spain Email: alvaro.miguel@gmail.com ORCID: https://orcid.org/0000-0003-3981-5699 Name: Saul Vallejos Calzada Institution: Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Plaza de Misael Bañuelos s/n, 09001 Burgos, Spain Email: svallejos@ubu.es ORCID: https://orcid.org/0000-0001-5522-6574 Name: José Miguel García Pérez Institution: Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Plaza de Misael Bañuelos s/n, 09001 Burgos, Spain Email: jmiguel@ubu.es ORCID: https://orcid.org/0000-0002-2674-8194 Name: Miriam Trigo López Institution: Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Plaza de Misael Bañuelos s/n, 09001 Burgos, Spain Email: mtrigo@ubu.es ORCID: https://orcid.org/0000-0001-5948-1230 DESCRIPTION ----------- 1. Dataset language English 2. Abstract: The dataset contains all raw data of the work "Boosting m-aramids performance with p-oriented aromatic amide side chains" 3. Keywords: Mechanical performance; thermal properties; hydrogen bonding; high performance; side chain; application in hydrogen environments. 4. Date of data collection 2023/2024 5. Date of dataset publication 2024-08-26 6. Funding This work was supported by the Regional Government of Castilla y León (Junta de Castilla y León), the Ministry of Science and Innovation MICIN and the European Union NextGenerationEU/PRTR, and the Spanish Agencia Estatal de Investigación (State Research Agency). Author M. Trigo-López received grant PID2019-108583RJ-I00 funded by MCIN/AEI/ 10.13039/501100011033. Álvaro Miguel received funding from Ministerio de Universidades-European Union in the frame of NextGenerationEU RD 289/2021 (CA1/RSUE/2021-00409) by the Universidad Autónoma de Madrid. 7. Geographic location/s of data collection Burgos (Spain) ACCESS INFORMATION ------------------ 1. Dataset Creative Commons License: CC 4.0 Internacional 2. Dataset DOI: XXXXXXXXXXXXX 3. Related publication The related article has been sent to: European Polymer Journal METHODOLOGICAL INFORMATION -------------------------- The 1H and 13C NMR spectra were aquired in deuterated DMSO using a Bruker Avance III HD spectrometer running at 300 MHz and 75 MHz, respectively. Mass spectrometry (MS) was acquired with an Agilent 6545 Q-TOF coupled with an electrospray ionization source (Agilent Jetstream Technology AJT-ESI). An FT/IR-4200 Jasco spectrometer with an ATR-PRO410-S single reflection accessory was used to record the intermediate and polymers’ infrared spectra (FTIR). The polymers' thermal and mechanical characterization was performed by: a) thermogravimetric analysis (Q50 TGA analyzer, TA Instruments) with around 5 mg of sample under synthetic air and nitrogen atmosphere at 10°C/min; b) differential scanning calorimetry, with 10 mg of the sample. The DSC method was performed as follows; first, the temperature was equilibrated at -80 °C/min; then, a ramp up to 300 °C at a speed of 10 °C/min was performed to delete the thermal history of the material. After that, the sample is cooled down to -80 °C at a speed of 10 °C/min. Lastly, the sample is heated to 300 °C and cooled at -80 °C at a speed of 10 °C/min. (Q200 DSC analyzer, TA Instruments), and c) tensile properties analysis of the samples (5×30 mm at 5 mm/min) (Shimadzu EZ Test Compact Table-Top Universal Tester). The films X-Ray diffraction spectra were attained using a D8 Discover DaVinci diffractometer (Bruker), coupled with a LINXEYE XE high-resolution energy-dispersive detector. The 2θ angle swept was measured from 2.5 to 90o, with a step size of 0.05o and 0.5 seconds per step. The Young’s moduli were locally measured using AFM microscopy (Cipher ES Environmental AFM, Oxford Instruments), using the AM–FM viscoelastic mapping mode as described in S. Benaglia, C.A. Amo, R. Garcia, Nanoscale. 11 (2019) 15289–15297. https://doi.org/10.1039/C9NR04396A. The microscope was equipped with a 160AC-NA tip (Opus, Mikromasch). FILE OVERVIEW -------------- "MS-m.xls" "MS-m.TXT" "MS-6.xls" "MS-6.TXT" "MS-5.XLS" "MS-5.TXT" "MS-4.xls" "MS-4.TXT" "MS-3.xls" "MS-3.TXT" "HNMR-m.txt" "HNMR-6.txt" "HNMR-5.txt" "HNMR-4.txt" "HNMR-3.txt" "HNMR-2.txt" "HNMR-1.txt" "FTIR-m.txt" "FTIR-6.txt" "FTIR-5.txt" "FTIR-4.txt" "FTIR-3.txt" "FTIR-2.txt" "FTIR-1.txt" "CNMR-m.txt" "CNMR-6.txt" "CNMR-5.txt" "CNMR-4.txt" "CNMR-3.txt" "CNMR-2.txt" "CNMR-1.txt" "CNMR-P1.txt" "CNMR-P10.txt" "CNMR-P20.txt" "CNMR-P50.txt" "DSC-P1.txt" "DSC-P10.txt" "DSC-P20.txt" "DSC-P50.txt" "FTIR-P1.txt" "FTIR-P10.txt" "FTIR-P20.txt" "FTIR-P50.txt" "HNMR-P1.txt" "HNMR-P10.txt" "HNMR-P20.txt" "HNMR-P50.txt" "MechanicalProperties-P1.txt" "MechanicalProperties-P10.txt" "MechanicalProperties-P20.txt" "TGAN2-P1.txt" "TGAN2-P10.txt" "TGAN2-P20.txt" "TGAN2-P50.txt" "TGAO2-P1.txt" "TGAO2-P10.txt" "TGAO2-P20 2%CAT Hidrogenated.txt" "TGAO2-P20 2%CAT NOHidrogenated.txt" "TGAO2-P20.txt" "TGAO2-P50.txt" "WaterUptake-P1.txt" "WaterUptake-P10.txt" "WaterUptake-P20.txt" "WaterUptake-P50.txt" "XRD-MPIA.xy" "XRD-P1.xy" "XRD-P10.xy" "XRD-P20.xy" "YoungModulus(AFM)-P20.xlsx" Short description: Each file is a .xlsx, .xy or a .txt file of each study/experiment