2026-09-07T23:20:29Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/105062026-05-13T10:21:56Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

00925njm 22002777a 4500 dc Hernández Ruiz, Raquel author Solas Luera, Marta author Suárez Pantiga, Samuel author Pedrosa Sáez, María de los Remedios author Sanz Díez, Roberto author 2025-05 A molybdenum-catalyzed deoxygenation of sulfoxides, pyridine and quinoline N-oxides, N-hydroxybenzotriazoles, as well as the reduction of nitroarenes to anilines, has been developed using monocyclic terpenes such as γ-terpinene as an environmentally benign hydrogen surrogate. The only byproducts generated are water and p-cymene, under neat reaction conditions in which the terpene acts as both solvent and reducing agent. These features make this approach a highly attractive and sustainable alternative for the reduction of S-O and N-O containing compounds. Additionally, the reaction exhibited excellent chemoselectivity, tolerating a wide variety of functional groups. 1615-4150 http://hdl.handle.net/10259/10506 10.1002/adsc.202401387 1615-4169 γ‐Terpinene Molybdenum Reduction Sulfoxides Nitroarenes γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N‐Oxides and Nitroarenes