2026-10-30T22:12:26Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/120262026-09-08T00:05:28Zcom_10259_4323com_10259_5086com_10259_2604col_10259_4330

Al Bodour, Ahmad fc3dc371-dd3c-4840-883b-69a1d1f21c63 Alomari, Noor 51ffd517-fe82-4928-a989-9b14f9d7a6c1 Pérez Durán, Guadalupe bc0f7fce-7a4a-4251-9ebc-fa5e0a46ff07 600 Rozas Azcona, Sara 779 600 0000-0003-2571-2971 Iglesias Silva, Gustavo A. 5dd41d03-57c1-4774-a6cf-a6efa846c20b 600 Aparicio Martínez, Santiago 30 600 0000-0001-9996-2426 Gutiérrez Vega, Alberto 271 600 0000-0003-2000-7413 Atilhan, Mert 51023856-6e72-4667-b27a-fe52e5115d61 600 2026-09-07T10:58:24Z 2026-09-07T10:58:24Z 2025-07 0887-0624 https://hdl.handle.net/10259/12026 10.1021/ACS.ENERGYFUELS.5C01280 1520-5029 Ionic liquids (ILs) are revolutionary materials composed entirely of ions and remaining liquid below 100 °C, often under ambient conditions. Their unique properties, including negligible vapor pressure, high thermal stability, and tunable structural characteristics, make them highly versatile. This review provides a comprehensive analysis of ILs by systematically exploring their physicochemical properties, such as density, viscosity, thermal stability, and phase behavior under various conditions. The impact of water on IL behavior, IL–IL mixtures, and structure–property relationships is critically examined. Technological applications, particularly in gas capture, energy storage, and drug delivery, are evaluated, alongside a techno-economic analysis discussing market dynamics, commercialization barriers, and lifecycle considerations. Environmental sustainability, biodegradability, and regulatory aspects are also assessed. By bridging fundamental understanding with application-driven insights, this review identifies pathways for advancing ILs as sustainable enablers of clean technologies. This work was funded by Agencia Estatal de Investigacion (Spain, PID2022-142405OB-I00), Consejeria de Educacion (Spain, BU047P23), and Western Michigan University Faculty Research and Creative Activities Award (FRACAA-230039670). Author Alberto Gutiérrez Vega received grant BG22/00089 funded by Spanish Ministerio de Universidades. The statements made herein are solely the responsibility of the authors. application/pdf eng ACS Publications Energy and Fuels. 2025, V. 39, n. 27, p. 12791-12829 https://doi.org/10.1021/acs.energyfuels.5c01280 Atribución 4.0 Internacional http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Cations Anions Solvents Transition temperature Salts Sales Salts Ionic liquids as multidimensional materials: A review from fundamentals to applications info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Energy & Fuels 39 27 12791 12829 THUMBNAIL Alomari-ef_2025.pdf.jpg Alomari-ef_2025.pdf.jpg IM Thumbnail image/jpeg 5276 https://riubu.ubu.es/bitstream/10259/12026/4/Alomari-ef_2025.pdf.jpg 40e603efe34a924e80720cc7e9fee19c MD5 4 LICENSE license.txt license.txt text/plain; charset=utf-8 998 https://riubu.ubu.es/bitstream/10259/12026/3/license.txt aa90105e1c90a1b4fe810649aa967b7d MD5 3 CC-LICENSE license_rdf license_rdf application/rdf+xml; charset=utf-8 908 https://riubu.ubu.es/bitstream/10259/12026/2/license_rdf 0175ea4a2d4caec4bbcc37e300941108 MD5 2 ORIGINAL Alomari-ef_2025.pdf Alomari-ef_2025.pdf application/pdf 4792181 https://riubu.ubu.es/bitstream/10259/12026/1/Alomari-ef_2025.pdf 02f8e57cebb2f70c36be2c694e22d15c MD5 1 10259/12026 oai:riubu.ubu.es:10259/12026 2026-09-08 02:05:28.789 Repositorio Institucional de la Universidad de Burgos bubrep@ubu.es RWwgYXV0b3IgY29tbyDDum5pY28gdGl0dWxhciBkZSBsb3MgZGVyZWNob3MgZGUgcHJvcGllZGFkIGludGVsZWN0dWFsIGRlIGxhIG9icmEsIG8gZGlzcG9uaWVuZG8gZGUgbG9zIGRlYmlkb3MgcGVybWlzb3MgZGUgbG9zIG90cm9zIHRpdHVsYXJlcywgc2kgbG9zIGh1YmllcmEsIHkgZW4gdmlydHVkIGRlIGxvcyBkZXJlY2hvcyBxdWUgbGUgY29uZmllcmUgbGEgbGVnaXNsYWNpw7NuIHZpZ2VudGUgc29icmUgcHJvcGllZGFkIGludGVsZWN0dWFsIHkgZGVyZWNob3MgZGUgYXV0b3IsIA0KQVVUT1JJWkEgYSBsYSBVbml2ZXJzaWRhZCBkZSBCdXJnb3MgYSBkaWZ1bmRpciwgZGUgbWFuZXJhIGdyYXR1aXRhLCBlbCBjb250ZW5pZG8gZGUgbG9zIGFyY2hpdm9zIGRpZ2l0YWxlcyBxdWUgY29ycmVzcG9uZGVuIGFsIGRvY3VtZW50byBkZXNjcml0byBhbnRlcmlvcm1lbnRlLCBjb24gY2Fyw6FjdGVyIG5vIGV4Y2x1c2l2byB5IGRlIG1hbmVyYSBww7pibGljYSBlbiBhY2Nlc28gYWJpZXJ0byBhIHRyYXbDqXMgZGUgSW50ZXJuZXQsIHBhcmEgbG8gcXVlIGxhIEJpYmxpb3RlY2EgcHJvY2VkZXLDoSBhIGFyY2hpdmFybG9zIGVuIGVsIFJlcG9zaXRvcmlvIEluc3RpdHVjaW9uYWwuIEFzaW1pc21vIGF1dG9yaXphIGEgbGEgVW5pdmVyc2lkYWQgZGUgQnVyZ29zIGEgcmVhbGl6YXIgbGFzIHRyYW5zZm9ybWFjaW9uZXMgbmVjZXNhcmlhcyBkZSBmb3JtYXRvLCBubyBkZSBjb250ZW5pZG8sIHBhcmEgZ2FyYW50aXphciBsYSBwcmVzZXJ2YWNpw7NuIHkgZWwgYWNjZXNvIGVuIGVsIGZ1dHVyby4NCg0KRWwgYXV0b3IgZGlzcG9uZSwgZW4gdG9kbyBjYXNvLCBkZWwgZGVyZWNobyBhIHJldm9jYXIgZXN0YSBhdXRvcml6YWNpw7NuLg0KDQpMYSBjZXNpw7NuIGRlIGRlcmVjaG9zIGRlIGVzdGEgb2JyYSBzZSBlbmN1ZW50cmEgc3VqZXRhIGEgbGEgbGVnaXNsYWNpw7NuIHZpZ2VudGUgc29icmUgcHJvcGllZGFkIGludGVsZWN0dWFsIHkgZGVyZWNob3MgZGUgYXV0b3I=