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oai:riubu.ubu.es:10259/38022022-12-20T11:04:13Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

2015-07-28T09:55:41Z urn:hdl:10259/3802 An unprecedented use for glycerol: chemoselective reducing agent for sulfoxides García Bartolomé, Nuria García García, Patricia Fernández Rodríguez, Manuel A. García, Daniel Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto A new application for glycerol that expands its possibilities beyond a green solvent and a precursor of value-added products has been demonstrated. Simple, easily available, and environmentally friendly dioxomolybdenum( VI) complexes are highly efficient catalysts for the chemoselective sulfoxide deoxygenation with this biomass-derived chemical feedstock. Both refined glycerol and crude glycerin can be used, thus expanding the potential application of this reaction. Subsequent transformation of glycerol during this reductive process has also been investigated 2015-07-28T09:55:41Z 2015-07-28T09:55:41Z 2013-02 info:eu-repo/semantics/article http://hdl.handle.net/10259/3802 10.1039/c3gc36908k eng Green Chemistry. 2013, V. 15, n. 4, p. 999-1005 http://pubs.rsc.org/en/journals/journalissues/gc#!recentarticles&adv info:eu-repo/grantAgreement/FEDER/CTQ2010-15358 info:eu-repo/grantAgreement/FEDER/CTQ2009-09949/BQU info:eu-repo/grantAgreement/JCyL/BU021A09 info:eu-repo/grantAgreement/JCyL/GR-172 info:eu-repo/semantics/openAccess Royal Society of Chemistry