2026-06-10T17:01:32Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/38022022-12-20T11:04:13Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

An unprecedented use for glycerol: chemoselective reducing agent for sulfoxides García Bartolomé, Nuria García García, Patricia Fernández Rodríguez, Manuel A. García, Daniel Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto Química orgánica Chemistry, Organic A new application for glycerol that expands its possibilities beyond a green solvent and a precursor of value-added products has been demonstrated. Simple, easily available, and environmentally friendly dioxomolybdenum( VI) complexes are highly efficient catalysts for the chemoselective sulfoxide deoxygenation with this biomass-derived chemical feedstock. Both refined glycerol and crude glycerin can be used, thus expanding the potential application of this reaction. Subsequent transformation of glycerol during this reductive process has also been investigated Ministerio de Ciencia e Innovacion (MICINN), FEDER (CTQ2010-15358 and CTQ2009-09949/BQU), Junta de Castilla y Leon (BU021A09 and GR-172), MICINN ("Juan de la Cierva" and "Ramon y Cajal" contracts for P.G.-G. and M.A.F.-R.) 2015-07-28T09:55:41Z 2015-07-28T09:55:41Z 2013-02 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion http://hdl.handle.net/10259/3802 10.1039/c3gc36908k eng Green Chemistry. 2013, V. 15, n. 4, p. 999-1005 http://pubs.rsc.org/en/journals/journalissues/gc#!recentarticles&adv info:eu-repo/grantAgreement/FEDER/CTQ2010-15358 info:eu-repo/grantAgreement/FEDER/CTQ2009-09949/BQU info:eu-repo/grantAgreement/JCyL/BU021A09 info:eu-repo/grantAgreement/JCyL/GR-172 info:eu-repo/semantics/openAccess application/pdf Royal Society of Chemistry