2026-06-19T14:58:53Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/38562021-11-10T09:38:17Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845
Repositorio Institucional de la Universidad de Burgos
author
Ibáñez Martínez, David
author
Plana, Daniela .
author
Heras, Aránzazu
author
Fermín, David J. .
author
Colina, Álvaro
2015-09-29T09:36:28Z
2015-09-29T09:36:28Z
2015-05
1388-2481
http://hdl.handle.net/10259/3856
10.1016/j.elecom.2015.02.012
In-situ Raman spectroscopy is implemented for the first time to monitor dynamic charge transfer processes at polarisable interfaces between two immiscible electrolyte solutions (ITIES) in real time. A custom-designed new electrochemical cell is described which allows probing the Raman signals of ferroin ions as a function of the potential applied across the water|1,2-dichlorobenzene (DCB) interface. This approach is also used for investigating the heterogeneous electron transfer reaction involving dimethylferrocene in DCB and potassium hexacyanoferrate (II/III) in the aqueous phase. The evolution of the Raman signals during potentiodynamic measurements is recorded in real-time with a resolution of a few seconds.
eng
Liquid/liquid interfaces
Ion transfer
Electron transfer
In-situ Raman spectroscopy
Monitoring charge transfer at polarisable liquid/liquid interfaces employing time-resolved Raman spectroelectrochemistry
info:eu-repo/semantics/article
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URL
https://riubu.ubu.es/bitstream/10259/3856/3/Ib%c3%a1%c3%b1ez-EC_2015.pdf
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https://riubu.ubu.es/bitstream/10259/3856/5/Ib%c3%a1%c3%b1ez-EC_2015.pdf.txt
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Ibáñez-EC_2015.pdf.txt