2026-06-19T12:20:38Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/38562021-11-10T09:38:17Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

Ibáñez Martínez, David Plana, Daniela . Heras, Aránzazu Fermín, David J. . Colina, Álvaro 2015-09-29T09:36:28Z 2015-09-29T09:36:28Z 2015-05 1388-2481 http://hdl.handle.net/10259/3856 10.1016/j.elecom.2015.02.012 In-situ Raman spectroscopy is implemented for the first time to monitor dynamic charge transfer processes at polarisable interfaces between two immiscible electrolyte solutions (ITIES) in real time. A custom-designed new electrochemical cell is described which allows probing the Raman signals of ferroin ions as a function of the potential applied across the water|1,2-dichlorobenzene (DCB) interface. This approach is also used for investigating the heterogeneous electron transfer reaction involving dimethylferrocene in DCB and potassium hexacyanoferrate (II/III) in the aqueous phase. The evolution of the Raman signals during potentiodynamic measurements is recorded in real-time with a resolution of a few seconds. eng http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Liquid/liquid interfaces Ion transfer Electron transfer In-situ Raman spectroscopy Monitoring charge transfer at polarisable liquid/liquid interfaces employing time-resolved Raman spectroelectrochemistry info:eu-repo/semantics/article