2026-05-30T04:15:22Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/38902022-04-29T11:09:58Zcom_10259_3593com_10259_5086com_10259_2604com_10259_3596col_10259_3594col_10259_3597

Pinacol as a new green reducing agent: molybdenum-catalyzed chemoselective reduction of sulfoxides and nitroaromatics García Bartolomé, Nuria García García, Patricia Fernández Rodríguez, Manuel A. Rubio Presa, Rubén Pedrosa Sáez, María de los Remedios Arnáiz García, Francisco Javier Sanz Díez, Roberto chemoselectivity molybdenum nitro compounds reduction sulfoxides Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions 2015-12-01T12:35:17Z 2015-12-01T12:35:17Z 2012-02 info:eu-repo/semantics/article 1615-4150 http://hdl.handle.net/10259/3890 10.1002/adsc.201100877 eng Advanced Synthesis & Catalysis. 2012, V. 354, n. 2-3, p. 321–327 http://dx.doi.org/10.1002/adsc.201100877 info:eu-repo/grantAgreement/MICINN/CTQ2010-15358 info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU info:eu-repo/grantAgreement/JCyL/BU021 A09 info:eu-repo/grantAgreement/JCyL/GR-172 info:eu-repo/semantics/openAccess Wiley-VCH Verlag