2026-06-07T02:33:21Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/38932022-12-20T11:48:42Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594

Sanjuán Cortázar, Ana María García García, Patricia Fernández Rodríguez, Manuel A. Sanz Díez, Roberto 2015-12-10T10:56:51Z 2015-12-10T10:56:51Z 2013-07 1615-4150 http://hdl.handle.net/10259/3893 10.1002/adsc.201300448 An asymmetric synthesis of elusive chiral cyclopentadienes has been developed by gold(I)-catalyzed alkoxycyclization of 1,3-dien-5-ynes. The application of these substrates in completely diastereoselective Diels–Alder cycloaddition reactions, which can be carried out in one pot from achiral 1,3-dien-5-ynes, allows the preparation of highly functionalized products bearing five stereogenic centers with high enantiomeric excesses eng info:eu-repo/semantics/openAccess cycloisomerization cyclopentadienes Diels–Alder reaction dienynes gold Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes info:eu-repo/semantics/article