2026-08-31T14:38:09Zhttps://riubu.ubu.es/oai/requestoai:riubu.ubu.es:10259/39082021-11-10T09:38:24Zcom_10259_3593com_10259_5086com_10259_2604col_10259_3594
Gold(I)-Catalyzed Tandem Cyclization–Selective Migration Reaction of 1,3-Dien-5-ynes: Regioselective Synthesis of Highly Substituted Benzenes
info:eu-repo/semantics/acceptedVersion
García García, Patricia
Martínez Cuezva, Alberto
Sanjuán Cortázar, Ana María
Fernández Rodríguez, Manuel A.
Sanz Díez, Roberto
Highly substituted benzene derivatives have been easily prepared in a regioselective way from readily available 1,3-hexadien-5-ynes through a gold(I)-catalyzed tandem reaction. The process involves an initial cyclization followed by a selective Wagner-Meerwein shift in which the migration preference seems to be determined by the ability to stabilize a positive charge
2016-01-20
2016-01-20
2011-08
info:eu-repo/semantics/article
1523-7060
http://hdl.handle.net/10259/3908
10.1021/ol202129n
eng
Organic Letters. 2011, V. 13, n. 18, p. 4970-4973
http://dx.doi.org/10.1021/ol202129n
info:eu-repo/grantAgreement/MICINN/CTQ2010-15358
info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
info:eu-repo/grantAgreement/JCyL/BU021A09
info:eu-repo/grantAgreement/JCyL/GR-172
info:eu-repo/semantics/openAccess
American Chemical Society