2026-07-30T23:18:12Zhttps://riubu.ubu.es/oai/request

oai:riubu.ubu.es:10259/42652021-11-10T09:38:17Zcom_10259_3844com_10259_5086com_10259_2604col_10259_3845

Fernández Blanco, Ana Cristina Colina, Álvaro Heras, Aránzazu 2016-11-11T09:02:21Z 2016-11-11T09:02:21Z 2013-05 1424-8220 http://hdl.handle.net/10259/4265 10.3390/s130505700 A new controlled current multipulse methodology has been developed to modify the screen-printed electrode surface with silver nanoparticles (AgNPs). Spectroelectrochemistry has provided not only information about the type of nanoparticles (NPs) deposited on the electrode surface, but also about the electrosynthesis process. Small NPs without plasmon band are initially generated. Next, these nuclei grow to form bigger NPs in the reduction pulses with a characteristic plasmon band centered at 400 nm. Most of the NPs are generated during the first reduction pulses and a linear growth of the absorbance at a lower reaction rate was obtained in the subsequent pulses. Oxidation pulses do not redissolve completely silver NPs but only partially, meaning that very stable NPs are generated. AgNPs-modified electrodes have been successfully used to determine hydrogen peroxide. Spectroelectrochemistry has also yielded very useful information to understand the voltammetric signal obtained during the reduction of H2O2 on silver modified electrodes. Ministerio de Economía y Competitividad (CTQ2010-17127) and Junta de Castilla y León (GR71, BU197A12-2) application/pdf eng MDPI Sensors. 2013, V. 13, n. 5, p. 5700-5711 http://dx.doi.org/10.3390/s130505700 info:eu-repo/grantAgreement/MINECO/CTQ2010-17127 info:eu-repo/grantAgreement/JCyL/GR71 info:eu-repo/grantAgreement/JCyL/BU197A12-2 Attribution 3.0 Unported http://creativecommons.org/licenses/by/3.0/ info:eu-repo/semantics/openAccess UV-Vis spectroelectrochemistry silver nanoparticles screen-printed electrodes electrochemistry Química analítica Chemistry, Analytic UV/Vis spectroelectrochemistry as a tool for monitoring the fabrication of sensors based on silver nanoparticle modified electrodes info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion